Australian Carbon
Dioxide Removal
Roadmap
November 2025
Citation and authorship
CSIRO (2025) Australian Carbon Dioxide Removal Roadmap.
CSIRO, Canberra.
This report was authored by CSIRO Futures and CSIRO
CarbonLock, with technical contributions made by
CSIRO researchers:
• Authors: Angus Grant, Persie Duong, Rohini Poonyth,
Philippa Clegg, David Newth, Vivek Srinivasan,
Andrew Lenton
• CSIRO technical contributors: Jim Austin, Renee Birchall,
Tess Dance, Ryan Gee, Andrew Higgins, Karsten Michael,
Doug Palfreyman, Andrew Ross, Anton Wasson,
Sam West, Morgan Williams
CSIRO Futures
At CSIRO Futures we bring together science, technology,
and economics to help governments and businesses
develop transformative strategies that tackle their biggest
challenges. As the strategic and economic advisory arm
of Australia’s national science agency, we are uniquely
positioned to transform complexity into clarity, uncertainty
into opportunity, and insights into action.
CSIRO CarbonLock
CarbonLock is Australia’s largest novel carbon dioxide
removal research program which brings together research
spanning engineering, biology and chemistry to search for
integrated CDR solutions. It leads Australia’s representation
in major global collaborations, and works closely with other
countries to further CDR solutions.
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Organisation 2025.
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CSIRO advises that the information contained in this
publication comprises general statements based on
research. The reader is advised and needs to be aware
that such information may be incomplete or unable to
be used in any specific situation. No reliance or actions
must therefore be made on that information without
seeking prior expert professional, scientific and technical
advice. To the extent permitted by law, CSIRO (including its
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Acknowledgement
CSIRO acknowledges the Traditional Owners of the land,
sea, and waters, of the area that we live and work on across
Australia. We acknowledge their continuing connection to
their culture, and we pay our respects to their Elders past
and present.
CSIRO and the authors are grateful to project partners and
experts who generously gave their time to provide input
to this project through Steering Committee meetings,
consultations, reviews and feedback as well as scientists
and researchers from CSIRO. This is a CSIRO report and
should not be taken as representing the views or policies
of project partners or other individuals or organisations
consulted. A full list of consulted stakeholders is available in
Appendix A1.
We would like to thank the researchers at the Lawrence
Livermore National Laboratory, who are the main authors of
the Roads to Removal report, for their guidance, advice and
feedback over the course of the project. We would also like
to specifically thank Mai Bui, Genevieve Holden, Wenqin Li
and Simon Pang for their advice and feedback.
Partners
Contents
Executive summary..................................................................................................................................iv
Part I: Introduction................................................................................................................11.1 Why do we need Carbon Dioxide Removal (CDR)?................................................................................................11.2 What is CDR?.............................................................................................................................................................21.3 How much CDR do we need?..................................................................................................................................41.4 Why do we need a portfolio approach?.................................................................................................................61.5 Australia’s resource potential..................................................................................................................................81.6 Report overview ......................................................................................................................................................9Part II: CO₂ capture and CO₂ storage...............................................................................112 Biological capture .............................................................................................................................122.1 Conventional biological capture ..........................................................................................................................122.2 Biomass carbon removal (BiCR) ............................................................................................................................143 Geochemical capture ....................................................................................................................213.1 Ocean alkalinity enhancement (OAE) ..................................................................................................................213.2 Enhanced rock weathering (ERW) .......................................................................................................................264 Chemical capture ............................................................................................................................304.1 Direct air capture (DAC) ........................................................................................................................................305 Geological storage ..........................................................................................................................355.1 Geological CO₂ storage .........................................................................................................................................356 Open environment storage .........................................................................................................386.1 Inorganic and organic carbon ..............................................................................................................................397 Mineral storage ................................................................................................................................447.1 Mineral carbonation .............................................................................................................................................447.2 Ex-situ mineral carbonation .................................................................................................................................46Part III: Capacity and cost analysis................................................................................498 Analytical scope and methodology........................................................................................508.1 Methodology .........................................................................................................................................................508.2 Outputs ..................................................................................................................................................................518.3 Regional constraints and inputs ...........................................................................................................................528.4 Known limitations .................................................................................................................................................619 Direct air capture + storage (DAC+S) ....................................................................................639.1 Overview ................................................................................................................................................................649.2 Australian capacity and costs for DAC+S .............................................................................................................649.3 Levers to influence CDR cost ................................................................................................................................679.4 Levers to influence CDR capacity..........................................................................................................................689.5 Other considerations ............................................................................................................................................71
10 Biomass carbon removal + storage (BiCR+S).....................................................................7210.1 Overview ................................................................................................................................................................7310.2 Australian capacity and costs for BiCR+S .............................................................................................................7310.3 Levers to influence CDR cost ................................................................................................................................7510.4 Levers to influence CDR capacity .........................................................................................................................7711 Ocean alkalinity enhancement (OAE)....................................................................................8011.1 Overview.................................................................................................................................................................8111.2 Australian capacity and costs for electrolytic OAE..............................................................................................8111.3 Levers to influence CDR cost ................................................................................................................................8311.4 Levers to influence CDR capacity..........................................................................................................................8511.5 Other considerations ............................................................................................................................................8812 Enhanced Rock Weathering (ERW) .......................................................................................8912.1 Overview ................................................................................................................................................................9012.2 Australian capacity and costs for agricultural ERW ............................................................................................9012.3 Levers to influence CDR cost ................................................................................................................................9212.4 Levers to influence CDR capacity..........................................................................................................................9612.5 Other considerations ............................................................................................................................................98Part IV: Actions and recommendations ....................................................................................9913 RD&D and scale-up considerations......................................................................................10013.1 DAC+S ...................................................................................................................................................................10113.2 BiCR+S ...................................................................................................................................................................10513.3 OAE........................................................................................................................................................................10913.4 ERW.......................................................................................................................................................................11213.5 Other RD&D opportunities..................................................................................................................................11614 Cross-cutting enablers ..................................................................................................................11715 Conclusion...........................................................................................................................................127Appendix...................................................................................................................................................128A.1 Stakeholder engagement list..............................................................................................................................128A.2 Glossary ................................................................................................................................................................129
Executive summary
Carbon Dioxide Removal (CDR)
is critical to reaching net zero.
CDR refers to human-facilitated activities that:
Remove carbon
dioxide (CO₂) from
the atmosphere.
+
Durably store it in
geological, land or ocean
reservoirs, or products.
To meet the goals of the Paris Agreement the world must
reach net zero emissions. However, achieving net zero is
only possible if countries simultaneously reduce emissions
and remove CO₂ from the atmosphere. Globally, it is
estimated that between 7–9 gigatonnes (Gt) of CO₂ per year
of CDR will be needed by 2050.1 In the near term, CDR must
complement, not replace, deep emissions reductions,
particularly in hard-to-abate sectors.2 Over the longer term,
CDR will play a key role in balancing residual emissions
and delivering net-negative outcomes needed to stabilise
the climate.
CDR approaches are grouped into two
broad categories: conventional and novel.
Conventional approaches, such as afforestation,
reforestation, and soil carbon sequestration, are already
contributing to Australia’s progress on climate change
and will deliver near-term removals and co‑benefits.
However, there is uncertainty around the scale and
composition of land based sequestration that may be taken
up as Australia transitions to net zero.3 These removals
can compete with other land uses such as agriculture or
biomass for low‑carbon fuels, may saturate over time, and
offer shorter term storage. They can also carry reversal
risks from climate-driven disturbances like droughts
and bushfires.4
Novel CDR approaches, by contrast, have the potential
to remove large volumes of CO₂ with a relatively small
land-footprint, and offer the potential for scalable and
durable storage over centuries to millennia. However, these
approaches are not yet at the scale needed and face
de‑risking challenges that include high costs, significant
energy and water requirements, and other dependencies.
1 About 25% of current global emissions (2024); which are estimated at 37.4 GtCO₂ (Global Carbon Project see: Friedlingstein P et al (2024) Global carbon
budget 2024. Earth System Science Data 17(3), 965–1039. ; 7–9 gigatonnes (Gt) of CO₂ sourced from
Smith SM, Geden O, Gidden MJ, Lamb WF, Nemet GF, Minx JC, Buck H, Burke J, Cox E, Edwards MR, Fuss S, Johnstone I, Müller-Hansen F, Pongratz J, Probst BS,
Roe S, Schenuit F, Schulte I, Vaughan NE (Eds) (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
2 Hard-to-abate emissions are emissions from sectors that are not easy to decarbonise with renewable technologies alone as these sectors often rely on
carbon from fossil fuels as building blocks for products (e.g. chemicals, plastics, steel), require high energy density fuels for long-distance transport (e.g.
aviation), or produce emissions inherently in their processes (cement production, agriculture in the form of methane).
3 Department of Climate Change, Energy, the Environment and Water (2025) Net Zero Report. DCCEEW, Canberra, ACT. .
4 Australian Climate Service (2025) Australia’s National Climate Risk Assessment. Australian Climate Service, Canberra, ACT. .
A portfolio of novel and
conventional CDR approaches
is required to reach net zero.
In Australia, it is projected that between
133–200 megatonnes (Mt) of CO₂ per year of CDR will be
needed by 2050, depending on how dramatically emissions
are reduced. These projections will not be achieved through
a single approach or technology. Both existing conventional
and novel CDR approaches will be needed.
Conventional CDR approaches will play an important role
in reaching net zero, due to their technical feasibility and
potential for deployment at scale. Given the magnitude,
complexity, and urgency of the climate challenge, a diverse
portfolio of solutions will be essential. This includes not
only established approaches but also the development of
novel CDR approaches.
A portfolio approach can help realise the opportunity
presented by emerging novel CDR to deliver durable
and scalable removals, while managing the near‑term
challenges with conventional CDR approaches
(see Figure 1-A). This is consistent with Australia’s Net Zero
Plan, which emphasises the importance of developing a
range of approaches beyond land-based options alone to
ensure a more robust net zero transition.5
This Roadmap quantifies Australia’s capacity for different
novel CDR approaches, their costs and what would be
needed to develop and deploy them at scale. It emphasises
how these approaches can complement conventional CDR,
especially as ongoing research and development reduces
their cost (see Figure 1-B). It also highlights the need for
ongoing collaboration and integration across scientific
disciplines to rigorously assess the efficacy and integrity
of each novel CDR approach, while also identifying their
co‑benefits and impacts on land, biodiversity, ecosystems
and resources.
Figure 1: (A) Stylised removal profile for conventional and novel CDR pathways. (B) Stylised CDR cost ranges over time (2025–2100),
anchored in the near term by market prices and in the mid-century by cost modelling from CSIRO’s 2024 Multi-sectoral
Modelling report6 and this report.
5 Department of Climate Change, Energy, the Environment and Water (2025) Net Zero Report. DCCEEW, Canberra, ACT. .
6 Green DL, et al., (2025) Multi-sectoral modelling 2024. CSIRO, Australia. .
Australia can responsibly harness
its rich natural and energy
resources to develop large-scale
novel CDR.
Australia is uniquely positioned for the deployment of
large-scale novel CDR, with advantages few other regions
or nations have. These include:
• Abundant land and mineral resources: ideal for biomass
cultivation and enhanced rock weathering at scale.
• Stable geological formations and one of the largest
marine estates: providing high-capacity, durable storage
both on land and in the ocean.
• Vast renewable energy potential: powering
energy‑intensive processes such as direct air capture
and ocean alkalinity enhancement.
• A highly skilled workforce in engineering and resources:
capable of designing, deploying and operating novel
CDR systems.
Australia could reach net zero
by using only a portion of its novel
CDR potential to complement
emissions reduction.
To inform decision making, this Roadmap examines four
CDR approaches, providing national capacity and cost
insights, highlighting key challenges, and recommending
pathways to greater maturity and lower costs.
Other developing approaches, such as ex-situ and in-situ
mineral carbonation, offer strong potential and will require
ongoing and future quantitative analysis.
The analysis found that, under conservative assumptions,
Australia has realisable capacity for up to 330 Mt of CO₂
removals per year by 2050, across all states and territories.
When combined with Australia’s conventional CDR
potential, Australia could surpass its projected national
requirements7 with only a portion of this identified
capacity. In many of these locations, Australian novel
CDR projects are already active, with 25 identified in
this analysis.
While the analysis highlights significant regional
opportunities for novel CDR, pursuing these opportunities
will require partnership with communities and must
occur alongside broader emissions reduction efforts.
The evidence and recommendations in this report
are intended to support informed decision making
that balances environmental, societal, cultural, and
economic needs.
In the next decade, Australia must build on global
efforts and invest in research to improve CDR maturity,
demonstrate performance, lower first-of-a-kind (FOAK)
plant costs, inform regional planning and build knowledge.
This Roadmap identifies key research areas to reduce risks,
understand co-benefits and enable the scale-up of novel
CDR in Australia. If constraints were to be relaxed under
a high ambition case, Australia’s capacity could almost
triple to 900 Mt of CO₂ per year.
7 Climate Change Authority (2024) Sector Pathways Review 2024. Commonwealth of Australia, Canberra. ; Climate Change Authority (2025) 2035 Targets Advice Report. Climate Change Authority,
Canberra, ACT.
Direct air capture + storage (DAC+S) encompasses many approaches that separate and remove CO₂ from
the atmosphere and store it durably. Solid adsorbent direct air capture and geological storage is one of two
representative DAC+S approaches considered in this Roadmap.
Realisable capacity
(MtCO2/y)
216 (excl. QLD)
High ambition capacity
(MtCO2/y)
453 (excl. QLD)
2050 cost ($/tCO2)
$400–480
Key research areas:
• Reduce capital costs.
• Conduct climate variability trials.
• Expand renewable energy capacity.
• Reduce operational costs.
• Verify geological storage.
Biomass carbon removal + storage (BiCR+S) includes approaches that transform biomass carbon into long-lived
products, or capture high-purity CO₂ from biomass carbon conversion and durably store it while producing energy
or other co-products. Biomass combustion to electricity and geological storage is one of two BiCR+S approaches
considered in this Roadmap.
Realisable capacity
(MtCO2/y)
88 (excl. QLD)
High ambition capacity
(MtCO2/y)
113 (excl. QLD)
2050 cost ($/tCO2)
$140–260
Key research areas:
• Develop a national biomass
inventory and allocation strategy.
• Implement cost effective
supply chains.
• Optimise process design.
• Verify geological storage.
Realisable
High ambition
Project site/head office
* The colour intensity of shaded areas and hatching indicates capacity,
with darker shades and denser hatching representing high capacity.
Realisable
High ambition
Project site/head office
* The colour intensity of shaded areas and hatching indicates capacity,
with darker shades and denser hatching representing high capacity.
Ocean alkalinity enhancement (OAE) refers to multiple ways to increase ocean carbon storage. It utilises the
naturally-occurring equilibrium reaction between atmospheric CO₂ and seawater. OAE allows additional atmospheric
CO₂ to be taken up by the ocean and durably stored. This Roadmap considers electrochemical ocean alkalinity
enhancement as a representative OAE approach.
Realisable capacity
(MtCO2/y)
7 (co-located)
High ambition capacity
(MtCO2/y)
114 (standalone)
2050 cost ($/tCO2)
80–140 (co-located
with existing
desalination plant)
$210–390
(standalone)
Key research areas:
• Determine site feasibility.
• Optimise electrolyser cost
and performance.
• Develop MRV for OAE.
Enhanced rock weathering (ERW) is a CDR approach that accelerates natural weathering processes to remove
atmospheric CO₂ and durably store it as stable carbonates and bicarbonates. This Roadmap considers agricultural
enhanced rock weathering as a representative ERW approach.
Realisable capacity
(MtCO2/y)
22
High ambition capacity
(MtCO2/y)
~220
2050 cost ($/tCO2)
$190–280
Key research areas:
• Improve MRV.
• Optimise supply chains.
• Understand carbon removal
potential and efficiency.
• Demonstrate opportunity for
farmers and landowners.
Realisable
High ambition
Project site/head office
* The colour intensity of shaded areas and hatching indicates capacity,
with darker shades and denser hatching representing high capacity.
Realisable
High ambition
Project site/head office
* The colour intensity of shaded areas and hatching indicates capacity,
with darker shades and denser hatching representing high capacity.
To realise the opportunity of novel CDR, Australia must build
the right enabling conditions.
The opportunity requires establishing a robust enabling environment that directs and supports the emergence
of a novel CDR industry in Australia. This Roadmap identifies a set of strategic actions that will nurture this
environment. These actions are inherently collaborative, requiring coordination between government, industry,
and research stakeholders. The recommendations are not exhaustive or prescriptive, but offer strategic direction
informed by international best practices and tailored to the Australian context:
Support the
development of
measurement, reporting
and verification (MRV)
across different novel
CDR approaches.
Position the scaling of
CDR and the need for a
portfolio of approaches
as a national strategic
priority alongside
emissions reduction.
Consider developing
a target for novel
CDR in Australia.
Include novel CDR
within an Australian
Carbon market.
Continue building
a strong science
evidence base
to support and
optimise novel CDR
deployments.
Accelerate
investment in novel
CDR along the
innovation pathway.
Leverage existing
hub-based models
and infrastructure.
Identify and coordinate
cost-effective and
zero‑emission CDR
supply chains.
Foster social
acceptance and
awareness for novel
CDR nationally and
regionally.
Ensure CDR projects
are developed in
partnership with
communities and
Traditional Owners.
Australia could establish itself as a global leader in novel CDR.
Australia is uniquely positioned to lead in novel CDR,
drawing on its rich natural resources, advanced industrial
base, skilled workforce, and strong global partnerships.
Together with targeted investment, novel CDR set Australia
on a pathway to:
• Meet its own net zero commitments while supporting
global climate goals.
• Create new industries that diversify the economy and
build regional resilience.
• Strengthen its international competitiveness in emerging
technologies and climate solutions.
• Create an opportunity in emerging international
carbon markets.
• Continue to play a leading role in global climate action.
The Roadmap lays out a clear vision for developing a novel
CDR industry in Australia, including the milestones and
actions needed over the next two decades. It highlights
regional opportunities for responsible CDR development
and aims to align government, industry and research
stakeholders to drive progress.
Part I: Introduction
1.1 Why do we need Carbon
Dioxide Removal (CDR)?
Removing significant amounts of CO₂ from the
atmosphere, combined with substantial emissions
reductions, will be required to meet the goals of the Paris
Agreement to limit global warming to well below 2°C
and achieve the internationally agreed‑upon ambition of
net zero greenhouse gas (GHG) emissions by 2050.
GHGs emitted as a result of human activities are continuing
to accumulate in the atmosphere. Concentrations of CO₂,
the most abundant long-lived anthropogenic GHG, now
exceed 423 parts per million (ppm),8 over 50% higher
than in the millennia preceding the Industrial Revolution.9
While rapid and significant emissions reductions are
a priority, these alone are now insufficient to reduce the
CO₂ concentration in the atmosphere and limit warming
to below 2°C.
In the near term, CDR is needed as a complement, rather
than a substitute, for emissions reductions, to reduce net
CO₂ emissions and achieve the net zero emission target
by 2050, according to the Intergovernmental Panel on
Climate Change’s (IPCC) Climate Change 2022: Mitigation
of Climate Change report.10 In the longer term (i.e. beyond
2050), CDR will play a critical role in counterbalancing
residual hard-to-abate emissions,11 as well as achieving
and sustaining net-negative emissions, a state in which
more CO₂ is removed from the atmosphere than emitted.
The effect of both CDR and GHG emissions on net emissions
is visualised in Figure 2.12
Figure 2: Stylised visualisation of the net effect of CDR relative to GHG emissions, to achieve net zero and net-negative GHG emissions.13
8 Cape Grim Greenhouse Gas Data (n.d.) Commonwealth Scientific and Industrial Research Organisation (CSIRO) Marine and Atmospheric Research and the
Australian Bureau of Meteorology (Cape Grim Baseline Air Pollution Station), Australia. .
9 Atmospheric CO₂ reached 422 ppm in December 2023, from approximately 280 ppm prior to the mid-18th century, which had been stable for millennia,
see; NASA (n.d.) Climate change: vital signs of the planet – carbon dioxide. ; CSIRO (n.d.) CO₂ data
and Twitter: how a tweet sparked a conversation about climate. ; Copernicus Climate Change Service (2025) 2024
is the first year to exceed 1.5°C above pre-industrial level. European Centre for Medium-Range Weather Forecasts (ECMWF), Reading, UK. .
10 IPCC (2022) Climate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental
Panel on Climate Change, p. 36. .
11 Hard-to-abate emissions are emissions from sectors that are not easy to decarbonise with renewable technologies alone as these sectors often rely on
carbon from fossil fuels as building blocks for products (e.g. chemicals, plastics, steel), require high energy density fuels for long-distance transport (e.g.
aviation), or produce emissions inherently in their processes (cement production, agriculture in the form of methane).
12 Chamberlain MA, Ziehn T, Law RM (2024) The Southern Ocean as the climate’s freight train – driving ongoing global warming under zero-emission scenarios
with ACCESS-ESM1. Biogeosciences 21, 3053–3073. .
13 Smith SM, Geden O, Gidden MJ, Lamb WF, Nemet GF, Minx JC, Buck H, Burke J, Cox E, Edwards MR, Fuss S, Johnstone I, Müller-Hansen F, Pongratz J, Probst BS,
Roe S, Schenuit F, Schulte I, Vaughan NE (Eds) (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
Global average temperatures are close to exceeding
the 1.5°C above pre-industrial levels target,14 and
there is an increasing likelihood of exceeding the 2°C
target.15 Therefore, as emissions continue to rise,16 it is
becoming clear that CDR will be needed to prevent a
potential temperature overshoot, which could have a
long-lasting and significant impact on the climate and
natural environments.17
1.2 What is CDR?
CDR removes CO₂ from the atmosphere and durably stores
it, creating negative emissions through a combination of
different capture and storage processes.
While the categorisation of CDR systems in the public
domain varies, this Roadmap adapts definitions from
The State of Carbon Dioxide Removal,18 and defines CDR
as human-facilitated activities that:
• remove CO₂ from the atmosphere
• durably store it in geological, land or ocean reservoirs,
or as long-lived products.
This Roadmap focuses on the removal of atmospheric CO₂,
rather than other non-CO₂ GHGs, due to the current lack
of scalable techniques to remove non-CO₂ GHGs from the
atmosphere. However, it is important to note that achieving
global net zero objectives requires the reduction and
removal of all forms of GHGs. For simplicity, quantities
of CDR in this Roadmap are expressed in terms of CO₂
(i.e. tonnes of CO₂, tCO₂, megatonnes of CO₂, MtCO₂ or
gigatonnes of CO₂, GtCO₂). Other emissions reduction and
CDR publications use units of measure that are expressed
in CO₂ equivalent (CO₂-e) terms. CO₂-e is a measure that
allows the emissions from non-CO₂ GHGs to be compared
on the basis of their global warming potential. It does this
by converting quantities of non-CO₂ GHGs to the equivalent
quantity of CO₂ with the same warming potential.
This Roadmap groups CDR approaches into two broad
categories: conventional CDR and novel CDR. Conventional
CDR refers to well-established approaches and activities
to remove CO₂ from the atmosphere.19 These approaches
typically leverage natural biological systems, including
afforestation, reforestation, and agroforestry. Conventional
CDR approaches are readily available, deployed at scale,
and have attained high technological maturity (technology
readiness level, or TRL,20 of 8–9). In contrast, novel CDR
refers to approaches that remove CO₂ from the atmosphere
and store it durably. To date, novel CDR approaches tend
to be deployed on a small scale and are less mature than
conventional CDR approaches.21
Durability in the context of CDR refers to the length of
time that captured CO₂ remains out of the atmosphere,
and it is a key factor differentiating conventional and novel
approaches. Durability can range from a few decades to
centuries or millennia.22 At a high level, conventional CDR
typically stores CO₂ for shorter timescales (i.e. decades to
centuries), and novel CDR approaches are often associated
with longer timescales ranging from centuries to millennia.23
14 Diffenbaugh NS, Barnes EA (2023) Data-driven predictions of the time remaining until critical global warming thresholds are reached. Proceedings of the
National Academy of Sciences of the United States of America 120(5), e2207183120. .
15 Diffenbaugh NS, Barnes EA (2023) Data-driven predictions of the time remaining until critical global warming thresholds are reached. Proceedings of
the National Academy of Sciences of the United States of America 120(5), e2207183120. ; IPCC (2018) Global
warming of 1.5°C. An IPCC Special Report on the impacts of global warming of 1.5°C above pre-industrial levels and related global greenhouse gas emission
pathways, in the context of strengthening the global response to the threat of climate change, sustainable development, and efforts to eradicate poverty.
World Meteorological Organization, Geneva, Switzerland. .
16 Friedlingstein P, O’Sullivan M, Jones MW, Andrew RM, Hauck J, Landschützer P, et al. (2025) Global Carbon Budget 2024. Earth System Science Data 17(3),
965–1039. .
17 Santana-Falcón Y, Yamamoto A, Lenton A, et al. (2023) Irreversible loss in marine ecosystem habitability after a temperature overshoot. Nature
Communications Earth & Environment 4, 343, .
18 Smith SM, Geden O, Gidden MJ, Lamb WF, Nemet GF, Minx JC, Powis C, Bellamy R, Callaghan M, Cowie A, Cox E, Fuss S, Gasser T, Grassi G, Greene J, Lueck S,
Mohan A, Müller-Hansen F, Peters G, Pratama Y, Repke T, Riahi K, Schenuit F, Steinhauser J, Strefler J, Valenzuela JM, Minx J (Eds) (2023) The State of Carbon
Dioxide Removal – 1st Edition. .
19 IPCC (n.d.) Task Force on National Greenhouse Gas Inventories (TFI). .
20 Technology readiness level (TRL) is a system to assess the maturity of a technology. TRL is often assessed based on a scale from 1 to 9, with 1 indicating the
technology is at a basic research level and 9 indicating the technology has been proven through successful operations in operating environment, and ready
for full commercial deployment. See; Department of Defence (n.d.) Technology Readiness Level (TRL) Explanations. Defence Science and Technology Group,
Australia. .
21 Smith SM, Geden O, Gidden MJ, Lamb WF, Nemet GF, Minx JC, Powis C, Bellamy R, Callaghan M, Cowie A, Cox E, Fuss S, Gasser T, Grassi G, Greene J, Lueck S,
Mohan A, Müller-Hansen F, Peters G, Pratama Y, Repke T, Riahi K, Schenuit F, Steinhauser J, Strefler J, Valenzuela JM, Minx J (Eds) (2023) The State of Carbon
Dioxide Removal – 1st Edition. .
22 Bergman A, Rinberg A (2021) The case for carbon dioxide removal: from science to justice. In Carbon Dioxide Removal Primer. .
23 Smith SM, et al (2023) The State of Carbon Dioxide Removal – 1st Edition. .
Achieving CDR involves two essential steps: capturing
CO₂ from the atmosphere and durably storing CO₂.
These steps can be implemented through various
combinations of capture and storage processes, each
with distinct technical characteristics, scalability, and
suitability depending on the context (see Figure 3).
For example, direct air capture (DAC) is a chemical CO₂
capture process that can be paired with geological
or mineral storage to form two different CDR
approaches. Given the rapidly evolving nature of the
global CDR landscape, Figure 3 is not exhaustive and
is designed to evolve as emerging processes and data
become available.
CDR represents one of the three key carbon
management pathways alongside Carbon Capture and
Storage (CCS) and Carbon Capture and Utilisation (CCU),
each with a unique but complementary role to help
Australia and the world achieve net zero ambitions.
CDR differs from other carbon management approaches
which generally seek to prevent carbon from entering
the atmosphere, versus CDR which seeks to provide
removals, or negative emissions outcomes. See Box 1 for
a summary of other carbon management pathways and
their interrelation with CDR.
Box 1: Carbon management.
CCS and CCU have shared processes and technology with
some CDR approaches and are two pathways that can
complement removal efforts within broader emissions
reduction strategies. CCS is the process of capturing CO₂
from a point source, such as a power plant or industrial
site, and durably storing it. CCU does the same but reuses
the CO₂ in products or industrial processes. Unlike CCS and
CCU, CDR systems result in additional net removal of CO₂
from the atmosphere, meaning they create atmospheric
removals that would not have happened without direct
intervention. Assessing additionality is a key feature of
CDR and is important to all carbon credit schemes.24
While all three carbon management pathways have a
role to play in achieving internationally agreed net zero
ambitions, CCS and CCU are out of scope for discussion
in this Roadmap. However, it is important to recognise
that capture, storage and utilisation processes can serve
complementary and dual purposes. For example, a DAC
system that captures and durably stores CO₂ from the
atmosphere is CDR. Alternatively, if it uses atmospheric
CO₂ to produce synthetic fuels, it is considered CCU.
As CO₂ capture and storage technologies advance, they
can support scaling across all carbon management
pathways and progress towards net zero.
Figure 3: Overview of various combinations of capture and storage processes or systems that make up different carbon management
pathways, including CDR, CCS and CCU.
CO₂ CAPTURE
CO₂ STORAGE
CO₂ UTILISATION
Geological storage
Mineral storage
Open
environments
Directly
used in
long-lived
products
Directly
used in
short-lived
products
CO₂ injection deep
underground
Above-ground
mineral
Below-ground
solid
Biologically
captured
during
biomass
growth
Via carbon
sequestration
in biomass
Via biomass
conversion
Geochemically
bound in minerals
Chemically
captured
as gas
From the air
From an
industrial
point source
Carbon Capture and Storage (CCS)
CO₂ captured from a point source and durably stored.
THIS ROADMAP
Carbon Dioxide Removal (CDR)
CO₂ removed from the atmosphere and durably stored in
geological, land or ocean reservoirs or as long-lived products.
Carbon Capture
and Utilisation (CCU)
CO₂ captured from
a point source or
the atmosphere and
used either directly
or indirectly to form
new products.
24 Climate Change Authority (2024) Coverage additionality and baselines. .
1.3 How much CDR do we need?
Under all net zero scenarios, significant and additional
CDR will be essential, globally and in Australia.
The precise level of global and Australian CDR required
will depend on a range of factors, including the current
and future costs of abatement, available CDR approaches
and their near-term adoption, the pace and extent of
emissions reduction efforts, as well as the availability and
development of low-emissions technologies.25
Most global estimates, including those from the IPCC,26
agree that billions of tonnes of CO₂ must be removed
annually worldwide. For example, the 2024 State of CDR
report suggested 7–9 Gt of CO₂ per year (GtCO₂/y) would
need to be removed from the atmosphere.27 The report also
estimated that 260 GtCO₂ would need to be cumulatively
removed between 2020 and the time of net zero emissions,
based on many IPCC scenarios that aim to limit warming
below 2°C.28 However, in other sustainable development
scenarios,29 a lower amount of 170 Gt of CO₂ would need to
be cumulatively removed, reflecting a more responsible and
sustainable pathway for CDR deployment.30
On average, around 2 Gt of CO₂ is being removed through
CDR globally, predominantly through conventional CDR
activities such as afforestation and reforestation.31 As of July
2025, the data sharing project CDR.fyi reported that credits
for 37 megatonnes (Mt) of novel CDR have been sold on
carbon markets and are committed to be removed, of which
2.2% have actually been removed and durably stored.32
In Australia, the Climate Change Authority (CCA) has
estimated that the country will need at least 133 Mt of
CO₂ removals by 2050 to achieve its national net zero
targets.33 Figure 4 illustrates possible emissions reduction
pathways under two selected CCA scenarios. Under these
scenarios, Australia will require anywhere between
133 and 200 Mt of CO₂ removals in 2050, depending on
the emissions reduction rate.34 However, the exact level
of CDR and mix of conventional and novel CDR required is
difficult to determine and highly sensitive to the modelling
assumptions used. Another recent study,35 with different
underpinning assumptions, estimated a similar overall level
of CDR required but at a greater reliance on novel CDR in its
“Net-zero Emissions by 2050” scenario.
The Australian Government, in its response to the CCA’s
2023 Annual Climate Change Statement, acknowledges
the need to incentivise the development of novel CDR by
supporting research, development and demonstration
(RD&D) through carbon markets or other financial
instruments, as well as by helping to reduce the domestic
and international regulatory barriers limiting its uptake.36
By supporting key CCA recommendations, the government
is recognising the role novel CDR can play in achieving
net zero.
25 Bergman A, Rinberg A (2021) The case for carbon dioxide removal: from science to justice. In Carbon Dioxide Removal Primer.
.
26 The review study, Fuss et al., finds that models estimate between 1.3 and 29 GtCO₂/y will be needed by 2050, with the most likely amount being between
5 and 15 GtCO₂y. See; Fuss S, Lamb WF, Callaghan MW, Hilaire J, Creutzig F, Amann T, Beringer T, de Oliveira Garcia W, Hartmann J, Khanna T, Luderer
G, Nemet GF, Rogelj J, Smith P, Vicente JL, Wilcox J, Zamora Dominguez MM, Minx JC (2018) Negative emissions—Part 2: Costs, potentials and side
effects. Environmental Research Letters 13(6), 063002. ; Minx JC, Lamb WF, Callaghan MW, Fuss S, Hilaire J,
Creutzig F, Amann T, Beringer T, de Oliveira Garcia W, Hartmann J, Khanna T, Lenzi D, Luderer G, Nemet GF, Rogelj J, Smith P, Torvanger A, Waller L, Weber E,
Wilcox J (2018) Negative Emissions Technologies and Reliable Sequestration: A Research Agenda. ;
27 Smith SM, Geden O, Gidden MJ, Lamb WF, Nemet GF, Minx JC, Buck H, Burke J, Cox E, Edwards MR, Fuss S, Johnstone I, Müller-Hansen F, Pongratz J, Probst BS,
Roe S, Schenuit F, Schulte I, Vaughan NE (Eds) (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
28 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
29 Scenarios refer to scientifically modelled storylines of a plausible future, based on many assumptions about the future evolution of demographics, economic
growth and technological progress, among others. IPCC scenarios are scenarios that are based primarily on IPCC temperature classifications and outcomes.
Sustainable development scenarios are a subset of scenarios that consider additional social and environmental sustainability criteria while also limit
global warming.
30 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
31 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
32 CDR.fyi (n.d.) .
33 Climate Change Authority (2024) Sector Pathways Review 2024. Commonwealth of Australia, Canberra. .
34 Climate Change Authority (2024) Sector Pathways Review 2024. Commonwealth of Australia, Canberra. ; Climate Change Authority (2025) 2035 Targets Advice Report. Climate Change Authority,
Canberra, ACT.
35 Nong D, Verikios G, Whitten S, et al. (2025) Early transition to near-zero emissions electricity and carbon dioxide removal is essential to achieve net-zero
emissions at a low cost in Australia. Communications Earth & Environment 6, 653. .
36 Department of Climate Change, Energy, the Environment and Water (2023) Annual Climate Change Statement 2023. .
Figure 4: Modelling of emissions reductions and CDR under two net zero scenarios.
The gross emissions (Mt CO₂-e) of seven sectors (land, electricity and energy, transport, industry and waste, built environment, agriculture and resources)
and carbon removals through novel CDR approaches together achieve net zero emissions by 2050 under two chosen scenarios. Scenario A50/G2 aligns
with Australia’s current targets, a 43% emissions reduction from 2005 levels by 2030 and net zero by 2050 in a world tracking towards 2°C of warming,
and Scenario A40/G1.5 aligns with faster emissions reductions in a world tracking towards 1.5°C of warming. Sourced from CSIRO modelling in AusTIMES,
commissioned by the Climate Change Authority (2024).37
37 Climate Change Authority (2024) Sector Pathways Review 2024. Commonwealth of Australia, Canberra. .
1.4 Why do we need a
portfolio approach?
No single CDR approach can achieve the required scale for
Australia to reach net zero by 2050. While it is expected
that conventional CDR will continue to provide near-term
benefits, novel CDR approaches are anticipated to be
favoured in the long term to achieve net zero and beyond.
Both conventional and novel CDR approaches face
limitations and are exposed to risks, underscoring that no
single approach can achieve the large-scale deployment
necessary to limit global warming below 2°C.
Conventional approaches, such as afforestation and
reforestation, are cost-effective in the near term, with
a global average cost of A$18–24 per tCO₂ removed.38
However, their storage potential saturates over time
(as shown in Figure 5), are land-intensive, and their
CO₂ removal capacity is inherently constrained by
land availability and competition with other primary
industries, such as agriculture and the production of
low‑carbon fuels.39
The profile in Figure 5 suggests additional land would
be required each year to maintain a constant rate of
conventional CDR over time, putting upward pressure on
land prices and costs. Similarly, it shows how conventional
CDR approaches tend to rely on storage in carbon stocks
that have a risk of reversal.40 According to Australia’s 2025
National Climate Risk Assessment Report,41 land‑based
mitigation options are increasingly compromised by
climate change and extreme events (e.g. bushfires, floods,
droughts, pests) or human-related activities (e.g. logging,
land-use change, urban area expansion).42
Figure 5: Stylised annual CO₂ removal profile for conventional
CDR per hectare of land.43
In contrast, novel CDR approaches offer durable storage
over much longer timescales, potentially exceeding
10,000 years. This is because novel CDR approaches store
CO₂ in less easily reversible forms, such as in geological
storage formations (see Section 5) or as stable carbonates
(see Section 7). However, novel CDR approaches are still
emerging and come with significant energy and resource
requirements, as well as high costs, especially in the
near term.44
For example, this Roadmap estimates that CDR via a
first‑of‑a-kind direct air capture and storage facility will
cost in excess of ~A$1,000 per tCO₂ in 2025 (see Section 9).
While costs are projected to significantly fall in the future,
this can only be realised with technological advancements,
as well as the support of market-related, cross-cutting
enablers to direct capital, enable cost-effective integration
with existing infrastructure, and build social acceptance
(see Section 14).
38 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
39 IPCC (2022) Climate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental
Panel on Climate Change. .
40 Caldecott B, Johnstone I (2024) The carbon removal budget: theory and practice. Journal of Environmental Policy & Planning 15(1), Article 2374515.
.
41 Australian Climate Service (2025) Australia’s National Climate Risk Assessment. Australian Climate Service, Canberra, ACT. .
42 Mota-Nieto J (2024) Carbon Dioxide Removal (CDR): A Key Pillar of Carbon Management and Sustainability. Energy Insight: 158. Oxford Institute for Energy
Studies, Oxford, UK. .
43 Profile based on average annual sequestration profile for mallee monoculture plantings from FullCAM. See: Department of Climate Change, Energy, the
Environment and Water (DCCEEW) (2024) Full Carbon Accounting Model (FullCAM). Commonwealth of Australia, Canberra. .
44 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
Figure 6 illustrates how a portfolio approach could be
required to manage risk and create future CDR optionality.
Figure 6 (A) provides a stylised removal profile for
conventional and novel CDR pathways, demonstrating the
discussed saturation that is expected with conventional CDR
over time. Figure 6 (B) depicts the cost-competitiveness of
conventional and novel removals over time. While future cost
trajectories cannot be predicted with certainty, the near-term
costs reflect the current market, while mid-century costs are
informed by CSIRO’s 2024 Multi-Sectoral Modelling report45
(for conventional CDR) and this Roadmap (for novel CDR).
These estimates do not explicitly account for durability
differences between conventional and novel approaches,
which will place additional value in a portfolio approach.
When viewed together, the capacity and cost profiles in
Figure 6 (A) and (B) highlight that a diverse mix of CDR
approaches will be essential. It will be important to optimise
the use of cheap and available conventional CDR in the near
term while supporting RD&D of novel CDR approaches to
reduce their costs and improve their scalability.
Figure 6: (A) Stylised removal profile for conventional and novel CDR pathways. (B) Stylised CDR cost ranges over time (2025–2100),
anchored in the near term by market prices and in the mid-century by cost modelling from CSIRO’s 2024 Multi-sectoral
Modelling report46 and this report.
45 Green DL, Reedman LJ, Kanudia A, Murugesan M, Dollman R, West S, Dioguardi E, Grant A, Nolan M, Singha D, Maxwell R, Li M, Havas L (2025) Multi-sectoral
modelling 2024. CSIRO, Australia. .
46 Green DL, et al., (2025) Multi-sectoral modelling 2024. CSIRO, Australia. .
1.5 Australia’s resource potential
Australia’s rich natural and energy assets offer
a globally unique platform to scale up both
conventional and novel CDR.
Australia is endowed with natural assets, including
abundant land and mineral resources, high-durability
geological basins and their significant CO₂ storage
capacities, a vast marine estate, and low-emission
energy opportunities. Together, these endowments
position Australia and create the opportunity for it to
be an early mover in global CDR markets, which are
projected to expand into a multi-billion to trillion-dollar
industry by 2050,47 encompassing both compliance and
voluntary markets. Combined with stable institutions
and a highly skilled engineering and natural resource
industry workforce, these advantages enable the near‑term
deployment of cost-effective conventional CDR, while
supporting development and scale-up of novel approaches
to reduce their costs and resource requirements over time.
The breadth of these advantages is illustrated in Figure 7
and explored further in Part III of the report.
Figure 7: A summary of Australia’s resource potential, including natural assets, land and mineral resources, geological basins,
marine estate and low-emission energy potential.
Globally competitive
renewable energy potential.
8.5 million km2 exclusive
economic zone, the 3rd
largest in the world.
Extensive mafic and ultramafic rock
reserves with additional potential for
reuse of mining residues.
Internationally recognised
geological storage potential.
Significant waste and residue
biomass resources.
650,000 km2 of pasture,
cropping and horticultural land.
47 Harrison K (2024) Carbon credits face biggest test yet, could reach $238/ton in 2050, according to BloombergNEF report. BloombergNEF, New York and
London. .
1.6 Report overview
This Roadmap aims to quantify Australia’s potential
to durably remove CO₂ from the atmosphere, helping
Australia develop a portfolio of solutions for carbon
removal. It provides an objective assessment of the cost,
scalability, measurement, reporting and verification
(MRV) requirements needed to support the deployment
of novel CDR approaches.
With conventional CDR already contributing to Australia’s
climate goals, this Roadmap builds an evidence base for the
potential to use novel CDR through transparent, objective
and proportionate economic analysis. It also looks to identify
the key actions required to scale up novel CDR in Australia,
across various approaches and RD&D timelines, as well
as cross-cutting enablers such as finance, policy, markets,
infrastructure and social and environmental engagement.
This Roadmap consists of four parts, as shown in Figure 8.
Part II explores CO₂ capture and CO₂ storage separately,
given the range of possible CDR combinations available
(see Figure 3). The section also aims to provide a foundation
for the cost and capacity analysis to follow. Part III outlines
the methodology used to assess Australia’s potential for
novel CDR and presents results for four representative
CDR approaches:
• Direct air capture and geological storage (DAC+S).
• Biological carbon removal and geological storage
(BiCR+S).
• Electrolytic ocean alkalinity enhancement (OAE).
• Agricultural enhanced rock weathering (ERW).
The Roadmap concludes with Part IV, which presents
actions and recommendations for the RD&D and scale-up
strategy for the four CDR approaches analysed, as well
as the cross-cutting enablers for the novel CDR industry
in Australia.
Figure 8: This Roadmap consists of four parts (Introduction, CO₂ capture and CO₂ storage, Capacity and cost analysis, and Actions
and recommendations).
Part II: CO₂ capture and
CO₂ storage
This part of the Roadmap examines processes that capture
and durably store CO₂, recognising that the integration
of both is required to create durable CDR approaches.
Figure 9 presents the taxonomy used to structure the
analysis, focusing solely on CDR-specific capture and
storage processes, which form a non-exhaustive selection
of CDR approaches. These approaches represent a subset
of broader carbon management approaches, which also
include CCS and CCU (see Figure 3, Section 1.2).
This Roadmap considers three forms of capture: biological
CO₂ capture (Section 2), geochemical CO₂ capture
(Section 3) and chemical CO₂ capture (Section 4) and three
CO₂ storage processes: geological storage (Section 5),
open environment storage (Section 6), mineral CO₂ storage
(Section 7). For each of the capture and storage processes
considered, this section provides an overview of the process
or system, focusing specifically on the approaches analysed
in this Roadmap (see Figure 9), and their current state of
development globally and in Australia. As a result, this
section is not considered an exhaustive discussion of all CO₂
storage processes relevant to the CDR landscape. While out
of scope for this Roadmap, information on conventional
CDR has been provided for completeness.
Figure 9: A summary of CDR approaches considered in this section of the Roadmap, including their durability.
CO₂ CAPTURE
CO₂ STORAGE
Geological storage
Mineral storage
Open environments
CO₂ injection deep
underground
Above-ground mineral
Below-ground solid
Biologically
captured during
biomass growth
Via carbon
sequestration
in biomass
Conventional CDR
10–100 years
Via biomass
conversion
BiCR+S – fast pyrolysis
to H2, combustion
>1,000 years
BiCR+S (ex-situ mineral
carbonation)
>1,000 years
BiCR+S (in-situ
mineral carbonation)
>1,000 years
BiCR+S – slow
pyrolysis to biochar
100–1,000 years
Geochemically bound in minerals
Ex-situ mineral
carbonation
>1,000 years
ERW
>1,000
years
OAE
>1,000
years
Chemically
captured as gas
From the air
DAC+S
(geological storage)
>1,000 years
DAC+S (ex-situ mineral
carbonation)
>1,000 years
DAC+S (in-situ mineral
carbonation)
>1,000 years
2 Biological capture
Biological CO₂ capture refers to the process of capturing
CO₂ during the growth of biomass. This section begins
with an exploration of biological capture used for
conventional CDR, followed by biomass carbon removal
(BiCR). Conventional biological capture describes
the well-established approaches that remove CO₂
from the atmosphere through biological processes
(i.e. photosynthesis). However, these biological processes
do not always result in the durable removal of CO₂,
for example, due to natural decomposition. In contrast,
BiCR is a novel capture process that converts biomass into
long-lived products and/or high-purity CO₂ for durable
geological and mineral storage (see Section 5–7).
2.1 Conventional biological
capture
Biological capture, or primary productivity, describes
well‑established, human-induced approaches to increase
the rate of CO₂ capture from the atmosphere through
biological processes (i.e. photosynthesis). This CO₂ is
then stored in plants, biomass and soil (see Section 6).48
Biological capture approaches underpin conventional
CDR and are currently deployed at scale globally as part
of land‑use, land-use change, and forestry activities.49
This section provides an overview of common biological
capture approaches and their state of development, as well
as the MRV considerations for carbon accounting.
2.1.1 Overview
Conventional biological capture approaches include,
but are not limited to, afforestation, reforestation and
agroforestry.50 Table 1 provides a high-level overview of
these approaches.
Table 1: Common conventional CDR approaches.51
APPROACH
DESCRIPTION
Afforestation
Conversion to forest of land that was not
previously forested.
Reforestation
Conversion to forest of land that was
previously deforested.
Agroforestry
Growing trees on agricultural land while
maintaining agricultural production systems.
Biological capture projects must consider the local context,
such as soil conditions and ecosystems, climate, land
ownership, and the project’s scale, establishment, and
maintenance. Any activities associated with agricultural
production also need to adapt to existing agricultural
practices, balancing between carbon capture and
maintaining agricultural productivity.52
Well-planned biological capture activities can yield
numerous environmental co-benefits, such as improving soil
health and quality, biodiversity, system resilience, as well
as enhanced forest and agricultural productivity. They can
also provide additional employment for local communities,
supporting local economies,53 although the net employment
impact will depend on the previous land use.
48 Smith SM, Geden O, Gidden MJ, Lamb WF, Nemet GF, Minx JC, Powis C, Bellamy R, Callaghan M, Cowie A, Cox E, Fuss S, Gasser T, Grassi G, Greene J, Lueck S,
Mohan A, Müller-Hansen F, Peters G, Pratama Y, Repke T, Riahi K, Schenuit F, Steinhauser J, Strefler J, Valenzuela JM, Minx J (Eds) (2023) The State of Carbon
Dioxide Removal – 1st Edition. .
49 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
50 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
51 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .; IPCC (2022) Climate Change 2022:
Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change.
.
52 IPCC (2022) Climate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental
Panel on Climate Change. .
53 IPCC (2022) Climate Change 2022: Mitigation of Climate Change. Contribution of Working Group III to the Sixth Assessment Report of the Intergovernmental
Panel on Climate Change. .
State of development
Biological capture approaches are mature (TRL 8–9)
and widely adopted, with many companies operating at
commercial scales in Australia and globally. This maturity
provides a potential near-term pathway for Australia and
the world to reach their net zero targets. At the same time,
broader decarbonisation is taking place and novel capture
approaches are being developed and scaled up.
Over the period between 2010 and 2020 in Australia,
biological capture activities had helped to remove a
substantial amount of CO₂ from the atmosphere, with
human-induced regeneration of native forests delivering
the highest average sequestration rate of 20 Mt of CO₂
per year (MtCO₂/y), followed by plantation and farm
forestry at 11.5 MtCO₂/y.54 By 2050, biological capture
activities have the potential to remove 74–130 MtCO₂/y
in Australia, according to CCA’s model of a Paris-aligned
net zero pathway for Australia.55 Globally, biological capture
activities are projected to remove 5.7 gigatons (Gt) of CO₂
by 2050, according to the 2024 State of Carbon Dioxide
Removal report.56
Globally, approximately 2.2 Gt of CO₂ were removed from
the atmosphere in 2022, the majority of which came
from biological capture activities, with less than 0.1%
(i.e. 1.35 Mt of CO₂) coming from novel capture processes.57
Afforestation and reforestation account for the majority
of global conventional CDR activities, most actively driven
by China, the collective European Union countries, the US,
Brazil, and the Russian Federation.58
2.1.2 MRV capture and storage
While many MRV protocols have been developed for
biological capture approaches globally, continued RD&D
will help strengthen methodologies for quantifying the
amount of CO₂ removed, enhance the consistency between
different protocols, and integrate advanced technologies
to improve MRV efficiency and reduce costs. As of 2024,
34 protocols had been developed for afforestation,
reforestation, agroforestry, and forest management.59
Different instruments (e.g. eddy covariance or chamber
systems), techniques (e.g. field sampling, remote sensing),
models (e.g. the Full Carbon Accounting Model, or FullCAM,
developed by the Australian Government Department of
Climate Change, Energy, the Environment and Water, or
DCCEEW60) and emission factors can be used together to
measure and quantify the total CO₂ removal of biological
capture activities.61
For the MRV of afforestation, reforestation and
agroforestry, challenges and uncertainties remain in
quantifying the CO₂ fluxes (i.e., emissions and removals)
from land use, land-use change, and forestry activities.62
There are also inconsistencies across different protocols
and countries in the distinction between natural and
anthropogenic CO₂ fluxes.63 Both factors have contributed
to general concerns from the public around the quality of
the carbon credits issued for these activities.64 Some MRV
approaches apply discounts to generated credits to account
for these uncertainties.
54 Fitch P, Battaglia M, Lenton A, Feron P, Gao L, Mei Y, Hortle A, Macdonald L, Pearce M, Occhipinti S, Roxburgh S, Steven A (2022) Australia’s sequestration
potential. CSIRO.
55 Climate Change Authority (2024) Sector Pathways Review 2024. Commonwealth of Australia, Canberra. .
56 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
57 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
58 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
59 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
60 Department of Climate Change, Energy, the Environment and Water (DCCEEW) (2024) Full Carbon Accounting Model (FullCAM). Commonwealth of Australia,
Canberra. .
61 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
62 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
63 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
64 Smith SM et al., (2024) The State of Carbon Dioxide Removal 2024 – 2nd Edition. .
2.2 Biomass carbon removal
(BiCR)
BiCR is a novel capture approach that builds upon
conventional biological CO₂ capture, enhancing the
durability of the stored carbon. Specifically, BiCR goes
further by converting biomass into high-purity CO₂ and
durably storing it in geological (see Section 5) or mineral
(see Section 7) storage, or converting biomass into
long‑lived products. This approach addresses the limitations
of conventional biological capture, which is vulnerable to
reversal through decomposition or disturbance, and aims to
secure carbon removal over much longer timescales.
Biomass conversion can co-produce energy products
(e.g. bioenergy, sustainable aviation fuel, other low-carbon
liquid fuels) and long-lived carbon products (e.g. biochar).
These products can be combusted and/or utilised for
energy generation, representing a CCU approach.
Alternatively, they can be stored in geological storage (in
the case of bio-oil) or in land-based open environments
(in the case of biochar, see Section 6), representing a CDR
approach (i.e. BiCR+S). Figure 10 summarises the possible
pathways of the BiCR+S approach, including those that
produce energy products, representing a combination of
CCU and CDR.
Biomass plays an important and cross-cutting role in the
global pathway to net zero emissions, supporting both
emissions reduction and CDR efforts. The use of biomass
to support CDR must be carefully managed to ensure
Australia’s biomass resources are used to maximise benefits
across communities, industries, and the environment
(see Box 2).
Figure 10: Overview of the BiCR+S approach.
Box 2: Australia’s biomass resources.
Australia has abundant biomass resources65 that could
be leveraged for CDR. The types of biomass feedstocks
considered in this Roadmap include:
• Agricultural biomass, including byproducts
from farming, such as crop residues (e.g. crop
stubbles and grasses) and processing wastes
(e.g. sugarcane bagasse).
• Forest residues, including unused residues from
primary and secondary mills, small-diameter trees and
logging residues from existing plantations.
• Municipal solid waste (MSW), including organic waste
generated by households, commercial activities and
industrial activities, with examples including paper
and cardboard, food wastes, and wood wastes.
• Biomass from short rotation trees (SRTs), such
as native perennial plants. SRTs can be grown to
supply additional biomass for CDR or integrated into
conventional farming and forestry systems.
The use of biomass feedstocks involves trade-offs and
must be carefully managed to avoid conflict with existing
land use, competing feedstock applications, and water
resource constraints. Feedstocks can be used in various
high-value applications that are often underappreciated.
For example, sugarcane bagasse is commonly burned at
sugar mills to generate onsite energy, so diverting it for
other uses would require alternative energy solutions.66
Biomass can also be used as a feedstock in the production
of sustainable aviation fuel and other low‑carbon liquid
fuels. Agricultural residues are often left on fields to
maintain soil health (i.e. nutrients, moisture, structure) or
used as animal feed.67 Similarly, retaining a manageable
amount of forestry residues in plantations is crucial for
supporting the local carbon cycle and biodiversity.68
Further details on the biomass feedstocks and their
specific considerations can be found in the Australian CDR
Roadmap – Modelling Appendix.
All of the biomass considered in this Roadmap is
waste or residue material, except SRT biomass. While
strategic planting could provide benefits to agricultural
productivity in terms of shelter and salinity,69 there are
also valid concerns about food security when agricultural
land is diverted to grow SRT crops.
While risks can potentially be mitigated, developing a
deeper understanding of Australia’s biomass feedstock
landscape is essential to unlock the country’s resource
potential and guide strategic decisions on the most
effective and sustainable uses of biomass resources.
Additionally, inputs from landowners, Traditional Owners
and producers are important in determining the best use
for their available biomass feedstocks based on market
demand, policy incentives, and local conditions.
65 Crawford DF, O’Connor MH, Jovanovic T, Herr A, Raison RJ, O’Connell DA, Baynes T (2015) A spatial assessment of potential biomass for bioenergy in
Australia in 2010, and possible expansion by 2030 and 2050. GCB Bioenergy 8(4), 707–722. .
66 CSIRO (2023) Sustainable Aviation Fuel Roadmap.
67 CSIRO (2023) Sustainable Aviation Fuel Roadmap.
68 CSIRO (2023) Sustainable Aviation Fuel Roadmap.
69 Crawford DF, O’Connor MH, Jovanovic T, Herr A, Raison RJ, O’Connell DA, Baynes T (2015) A spatial assessment of potential biomass for bioenergy in
Australia in 2010, and possible expansion by 2030 and 2050. GCB Bioenergy 8(4), 707–722. .
2.2.1 Overview
BiCR processes involve the conversion of biomass and can
be based on thermochemical or biological mechanisms.
This section provides a high-level explanation and state
of development discussion of three mature (high TRLs)
thermochemical BiCR processes, including:
• Slow pyrolysis to biochar, which operates at lower
temperatures over longer durations to produce biochar,
a stable form of carbon storage, along with a syngas
byproduct.
• Fast pyrolysis to hydrogen (H₂), which uses higher
temperatures over short timescales to yield bio-oil and
some biochar, along with a syngas byproduct containing
CO₂ that is captured and durably stored.
• Combustion to electricity, which combusts biomass to
generate electricity while capturing CO₂ for storage.
This is followed by a high-level overview of emerging and
alternative BiCR processes that have the potential to lower
energy costs, optimise the use of biomass resources, and
better align with region-specific needs.
Slow pyrolysis to biochar
The slow pyrolysis process applies heat at around 400°C
to the biomass in the absence of oxygen (O₂) and over a
timescale of minutes to days, producing predominantly
biochar (Figure 11).70 Biochar is a porous carbon product
made up of typically 12–25% of the total biomass’s carbon,
depending on the feedstock.71 Biochar can be applied to soil
as a long-lived carbon product, allowing CO₂ to be durably
stored (see Section 6.1.2: Organic carbon, Biochar). The syngas
byproduct of the slow pyrolysis process can be combusted
for heat, releasing CO₂ gas that may or may not be captured
depending on the scale of the operation and the economic
viability of integrating carbon capture and storage processes.
The state of development of CDR operations using biochar
can be found in Section 6.1.2: Organic carbon, Biochar.
Figure 11: Overview of the slow pyrolysis process.
Note: Suitable biomass includes low-moisture, low-ash agricultural and forestry residues and MSW; carbon crop biomass.
Fast pyrolysis to H₂
The fast pyrolysis process requires temperatures of
500–650°C and a reaction timescale of seconds to produce
high bio-oil yields and a small amount of biochar.72 The high
yields of bio‑oil enable subsequent upgrading pathways
into H₂, liquid fuels (i.e. gasoline and diesel), or bio-asphalt
(Figure 12).73
Depending on the bio-oil upgrading pathway, fast pyrolysis
processes can achieve a CDR potential exceeding 1.6 tCO₂
per dry tonne of biomass.74 The pathway producing H₂ has
the highest CDR rate (i.e. up to 100% of carbon in biomass
can be captured and stored), followed by the pathway
producing liquid fuels (i.e. 67% of carbon in biomass
can be captured and stored), and lastly, the pathway
producing bio‑asphalt (i.e. 57–74% of carbon in biomass
can be captured and stored).75 In general, the fast pyrolysis
processes shown in Figure 12 capture a greater proportion
of the carbon content of biomass than the slow pyrolysis to
biochar process shown in Figure 11.
70 Al-Rumaihi A, Shahbaz M, Mckay G, Mackey H, Al-Ansari T (2022) A review of pyrolysis technologies and feedstock: A blending approach for plastic and
biomass towards optimum biochar yield. Renewable and Sustainable Energy Reviews 167, 112715. .
71 Pett-Ridge J, Kuebbing S, Mayer AC, Hovorka S, Pilorgé H, Baker SE, et al. (2023) Roads to Removal: Options for Carbon Dioxide Removal in the United States.
Report No. LLNL-TR-852901. Lawrence Livermore National Laboratory (LLNL), Livermore, CA, United States. .
72 Al-Rumaihi A, et al (2022) A review of pyrolysis technologies and feedstock: A blending approach for plastic and biomass towards optimum biochar yield.
.
73 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
74 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
75 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
Figure 12: Overview of the fast pyrolysis process.76
Note: Suitable biomass includes low-moisture,
low-ash agricultural and forestry residues and
MSW; carbon crop biomass.
State of development
There have been increasing efforts to demonstrate and
scale up fast pyrolysis in industry globally, and emerging
attention to its potential for CDR purposes.77 An example
of a commercial fast pyrolysis operator with a CDR focus is
Charm Industrial (US). The company has developed a fast
pyrolysis process for agricultural and forestry wastes and
residues to produce bio-oil that is injected and durably
stored underground, as well as biochar.78
In 2024, Charm Industrial commissioned eight pyrolysers,
each capable of producing 0.5 tonnes of bio-oil and 0.2
tonnes of biochar from one tonne of biomass, equivalent to
capturing one tonne of CO₂.79 In May 2023, Charm Industrial
had its first offtake agreement with advanced market
commitment Frontier to remove 112,000 tCO₂ via bio-oil
between 2024 and 2030.80 In January 2025, the company
signed an agreement with Google to remove 100,000 tCO₂
through 2030 via biochar.81 Charm Industrial also actively
drives MRV advancements, working in partnership with
Isometric to develop high-quality standards and practices
and an open digital MRV system for transparency and
knowledge sharing.82
Combustion to electricity
Combustion is a single-step heating process that
produces steam and electricity alongside CO₂ (Figure 13).83
The combustion process involves fewer and less complex
steps than that of fast pyrolysis to H₂, and consequently has
lower capital investment requirements and less process risk.
76 Smart S, Ashman P, Scholes C, Tabatabaei M, Hosseini T, Yee R, McConnachie M, Sheil A, Jackson T, Beiraghi J (2023) Technoeconomic Modelling of Future
Fuel Production Pathways: Summary Report. Future Fuels CRC, RP1.2-02, The University of Queensland, The University of Adelaide, The University of
Melbourne, Australia. .
77 Hrbek J (2022) Status Report on Thermal Gasification of Biomass and Waste 2021. IEA Bioenergy Task 33, University of Natural Resources and Life Sciences
Vienna (BOKU), Austria. .
78 Charm Industrial (n.d.) FAQ and Protocols for Bio-oil Sequestration. .
79 Reinhardt P (2024) The Charm Underground: 2024 Year in Review. Charm Industrial. .
80 Frontier Climate (2023) First Offtake: Frontier buyers sign $53M in agreements with Charm Industrial. .
81 Cohn H (2024) The Charm duo: Charm bio-oil and Charm biochar. Charm Industrial. .
82 Cohn H (2024) Charm delivers first-ever Isometric verified carbon removals to Stripe, Shopify, JP Morgan Chase. ; Charm Industrial (n.d.) ;
Charm Industrial (2024) Introducing Ledger: A system for reliably monitoring & reporting biomass carbon removal at scale. .
83 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory. .
However, the steam and electricity products are commodities
that can be produced by a range of other low-cost
processes.84 Relatively high CDR potential of 1.6 tCO₂ per dry
tonne of biomass can be achieved through this process.85
State of development
The ability to convert conventional power plants powered
by fossil fuel combustion to those powered by biomass
combustion, along with the flexibility towards different
biomass feedstocks, are two driving factors enabling
biomass combustion processes to be adopted and scaled
up globally.
In March 2025, Stockholm Exergi (Sweden) announced
the decision to build one of the world’s largest biomass
combustion facilities with CCS processes integrated,
building on the operation of a test facility since 2019
which was used to demonstrate and prove its capture
process. The commercial-scale facility is expected to be
operational in 2028, with a capacity to capture and durably
store 800,000 tonnes of CO₂ per year (tCO₂/y) from
the atmosphere.86
The Danish Government has been investing heavily in
projects to help reduce Denmark’s annual CO₂ emissions
by 2.3 Mt from 2030.87 In 2023, Ørsted Bioenergy was
awarded the first contract under the public funding scheme
to integrate CO₂ capture processes into its straw- and
woodchip-fired power plants. The refurbished power
plants are expected to be operational by 2026, capturing
430,000 tCO₂/y from the atmosphere and delivering
3.67 Mt of certified carbon removal for Microsoft.88
Similarly, Drax (United Kingdom, or UK) has been piloting
and scaling up CO₂ capture and storage processes to
integrate into its existing biomass power plant, which
combusts byproducts and wastes from timber and forest
industries. Drax plans to convert two operating units at its
Power Station for CO₂ capture purposes, with the capacity
to remove 8 MtCO₂/y once operational in 2030.89
Toshiba Energy Systems and Solutions (ESS) Corporation
(Japan) has also integrated CO₂ capture and storage
processes into its Mikawa Power Plant, powered by palm
kernel shells. The commercial-scale facility commenced
operation in 2020, capturing 500 tCO₂ per day.
The captured CO₂ is planned to be liquified and stored at
an offsite CO₂ storage, with ongoing RD&D since 2021.90
In 2016, the company also operated a pilot facility at a
municipal waste incineration plant, capturing 10 tCO₂
per day and utilising end CO₂ products for crop cultivation
and algaculture.91
Figure 13: Overview of the combustion to electricity process.92
Note: Suitable biomass includes low-moisture, low-ash agricultural and forestry residues and MSW; carbon crop biomass.
84 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
85 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
86 Stockholm Exergi (2025) Stockholm Exergi to build one of the world’s largest facilities for removing carbon dioxide from the atmosphere.
.
87 Danish Energy Agency (2024) Danish Energy Agency presses the start button for billion-dollar tendering procedure for carbon capture and storage.
.
88 Ørsted (n.d.) Carbon capture and storage. .
89 Baringa Partners LLP (2025) Value for Money Assessment of the Low-Carbon Dispatchable CfD for Drax Power Station. Drax Group, Selby, UK.
; Drax Group (n.d.) BECCS at Drax: the process.
.
90 Kitamura H, Iwasa K, Fujita K, Muraoka D (2022) CO₂ Capture Project Integrated with Mikawa Biomass Power Plant: Case Study. Toshiba Energy Systems &
Solutions Corporation, Yokohama, Japan. .
91 Toshiba Energy Systems & Solutions Corporation (n.d.) Efforts for CO₂ emission reduction – CO₂ capture technology. .
92 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
2.2.2 Emerging and alternative BiCR processes
There are many emerging and alternative BiCR processes based on less advanced thermochemical, biological and
other mechanisms, with the potential to lower energy costs, optimise the use of biogenic resources, and better
align with region-specific needs. Some of these processes require further RD&D and scale-up support (see Table 2).
The summary has been developed based on the US Roads to Removal report.
Table 2: Overview of emerging and alternative BiCR processes.93
PROCESS
DESCRIPTION
KEY RD&D CHALLENGES
Gasification
Gasification is the process of decomposing biomass into syngas,
which comprises carbon monoxide, H₂, CO₂ and a small amount
of methane. Syngas can be further upgraded into liquid fuels
(e.g. sustainable aviation fuel, gasoline, and diesel), H₂, or
renewable natural gas.94
Of the syngas upgrading pathways, up to 100% of carbon in
biomass can be captured and stored if H₂ is produced, equivalent
to the CDR potential of approximately 1.50–1.85 tCO₂ per dry
tonne of biomass. Pathways that produce liquid fuels and
renewable natural gas can convert 26–36% of the carbon in
biomass into fuels, with the remaining proportion (64–74% of the
carbon in biomass) potentially being captured and stored.95
Gasification has been developed and demonstrated in industry
for both CDR and CCU purposes. An example gasification
operator is UK-based Kew Technology, which has constructed
a commercial‑scale gasification facility with integrated carbon
capture. The facility consists of many high-pressure, modular
units, each of which can process 15,000 tonnes of feedstock per
year, generate 4 megawatts (MW) of energy output as H₂ product
(at a rate of 120 kg per hour), and remove 20,000 tCO₂/y from
the atmosphere.96
Complex and expensive post-
gasification clean up; requirement for
consistent feedstock and centralised
processing requirement.97
Hydrothermal
liquefaction
Hydrothermal liquefaction is a thermochemical process that
converts biomass into liquid fuels at moderate temperatures
(250–375°C) and operating pressures of 4–22 MPa. It has the
advantage of being able to process high-moisture biomass such
as manure and food waste.
CO₂ can be captured from the off-gas generated during the
hydrothermal liquefaction process, and from the off‑gas produced
during the steam methane reforming step to produce H₂.
Limited efficiency in capturing and storing
all the carbon in biomass that is not
converted into chemicals, fuels, or energy;
high-pressure requirement; low-durability
char produced compared to biochar.
Biological processes
Biological processes utilise microorganisms and/or enzymes to
convert biomass into fuels or renewable natural gas. Notable
processes include fermentation and anaerobic digestion.
Fermentation: Sustaining economic
viability, high capital and operating costs.
Anaerobic digestion: Limited CDR
efficiency per unit biomass feedstock.
93 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
94 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
95 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
96 KEW Technology Ltd (2022) Direct Air Capture Programme: CCH₂ – Carbon Capture and Hydrogen. Department for Business, Energy and Industrial Strategy,
London, UK. ; KEW Technology Ltd (n.d.) Our technology. .
97 CSIRO (2023) Sustainable Aviation Fuel Roadmap.
2.2.3 MRV capture and storage
Several MRV protocols have been developed to allow CDR
via BiCR+S to be sold through voluntary carbon markets.
Isometric, a carbon removal registry, has developed the
Biogenic Carbon Capture and Storage protocol, which
applies to the BiCR processes covered by the scope of this
analysis.98 This section draws primarily on the Isometric
protocol to illustrate MRV requirements for BiCR+S, and
all MRV-related insights presented here are based on
this protocol unless otherwise specified. The decision
to primarily draw on Isometric protocols, rather than
those of other organisations, for BiCR+S and other novel
CDR approaches in scope is due to Isometric being a
highly regarded global expert in MRV for CDR and having
developed a wide range of protocols. This enables a simple
but consistent structure to present how net CO₂ removal
is calculated and to illustrate the MRV nuances between
different novel CDR approaches.
Using the Isometric protocol, the net CO₂ removal is
calculated based on the total CO₂ removed from the
atmosphere and durably stored as biogenic carbon,
excluding the amount of counterfactual CO₂ and any direct
CO₂ emissions from the project.
The total amount of CO₂ removed from the atmosphere and
durably stored as biogenic carbon can be measured and
calculated depending on the selected storage method for
CO₂, such as geological storage or ex-situ or in-situ mineral
carbonation (see Section 5–7).
Calculations of counterfactual CO₂ account for the
CO₂ stored in the biomass feedstock that would have
remained durably stored in the biomass in the absence of
the project, as biomass feedstock is a CO₂ storage medium
on its own, despite the limited durability.
Direct CO₂ emissions from the project are associated with
its establishment and operation (including energy use),
end-of-life activities such as MRV, embodied emissions in
the production and transportation of feedstock, equipment,
and materials to the facility, and any leakage emissions.
Leakage emissions represent increased emissions that
occur when feedstock production increases in response to
increased demand or additional activities are required to
replace current feedstock uses.
The Isometric protocol requires the project to consider
unique elements of BiCR+S, including the additionality of
CDR and the non-additionality of co-product production
facilities, as well as the emissions related to reagent
use and disposal, and the purity and concentration of
CO₂. Uncertainties associated with the MRV of BiCR+S
also need to be considered and accounted for, including
the measurement error related to fuel combustion, the
production of capture materials, and the production and
processing of biomass feedstocks.99
98 Isometric (n.d.) Biogenic Capture and Storage Protocol v1.1. ; Isometric (n.d.) Biomass Feedstock Accounting Module v1.3. .
99 Verra (2025) CO₂ Capture from Bioenergy: VCS Module VMD0059. Verified Carbon Standard Program, Washington, DC, USA. .
3 Geochemical capture
Geochemical CO₂ capture removes CO₂ from the
atmosphere through interactions with Earth’s natural
carbon cycle, including land and ocean sinks. This section
focuses on two groups of human-induced capture processes
that increase the natural rate of geochemical CO₂ capture.
The first group of processes accelerates the natural marine
carbon cycle by enhancing the ocean’s capacity to absorb
additional atmospheric CO₂,100 forming the basis of the
ocean alkalinity enhancement (OAE) approach. The second
group of processes, known as enhanced rock weathering
(ERW), accelerates the reaction between atmospheric CO₂
dissolved in rainwater as carbonic acid and calcium- and
magnesium-rich silicate rocks, by crushing and deliberately
dispersing these rocks on large areas of land.101
3.1 Ocean alkalinity
enhancement (OAE)
The ocean currently removes approximately 26% of
the annual anthropogenic emissions of CO₂ from the
atmosphere, acting as a carbon sink.102 The exchange of
CO₂ between the ocean and the atmosphere is controlled
by a combination of physical, chemical, biological and
geological processes.103 When CO₂ reacts with seawater,
a small amount (~1%) remains as aqueous CO₂, while the
remaining portion is converted to dissolved inorganic
carbon in the form of bicarbonate ions (HCO₃-) and
carbonate ions (CO₃2-),104 both of which are durable forms of
CO₂ storage105 (see Section 6).
The amount stored in each form of CO₂ is a function of the
seawater pH (Figure 14), with the carbonate system acting
as a natural buffer for the seawater pH.106 For example, if
a source of acidity is added to seawater, bicarbonate and
carbonate ions are converted into CO₂, and some of this CO₂
is released back to the atmosphere, minimising the change
in seawater pH. When a source of alkalinity is added, the
opposite reaction takes place, in which dissolved CO₂ is
converted into bicarbonate and carbonate ions, leading to
the drawdown of additional CO₂ from the atmosphere.
OAE approaches take advantage of this interaction between
different forms of CO₂ and seawater pH to enhance the
ocean’s capacity to absorb additional atmospheric CO₂
and durably store it as carbonate and bicarbonate ions.107
This section provides an overview of different OAE
approaches with a focus on a closed-loop electrolytic OAE
approach in more detail. It is recognised that separating
OAE into distinct CO₂ capture and storage components is
challenging, due to the inherent chemistry and dynamics of
the ocean system. For this section, CO₂ capture refers to the
increased capacity of seawater to absorb CO₂.
Figure 14: Relationship between ocean carbonate chemistry
and pH.108
Note: Bjerrum plot shows the relative proportions of [HCO₃-], [CO₃2-] and
[CO₂] to dissolved inorganic carbon in seawater at temperature T = 25°C,
salinity S = 35%, and pressure P = 0 bar. The shaded region reflects the
annual average pH range of the ocean surface, while the hashed region
reflects the ocean surface pH range from the global ocean geochemistry
model projections of Turley et al. (2010).
100 GESAMP (2019) High level review of a wide range of proposed marine geoengineering techniques. (Eds. PW Boyd, CMG Vivian). IMO/FAO/UNESCO-IOC/
UNIDO/WMO/IAEA/UN/UN Environment/UNDP/ISA Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection, Rep. Stud. GESAMP
No. 98. .
101 Holden FJ, Davies K, Bird MI, Hume R, Green H, Beerling DJ, Nelson PN (2024) In-field carbon dioxide removal via weathering of crushed basalt applied to
acidic tropical agricultural soil. Science of the Total Environment 955, 176568. .
102 Friedlingstein P et al (2025) Global Carbon Budget 2024. Earth System Science Data 17, 965–1039. .
103 Gruber N, Bakker DCE, DeVries T, Gregor L, Hauck J, Landschützer P, McKinley GA, Müller JD (2023) Trends and variability in the ocean carbon sink. Nature
Reviews Earth & Environment 4, 119–134. .
104 Dickson AG (2010) The carbon dioxide system in seawater: equilibrium chemistry and measurements. In Guide to best practices for ocean acidification
research and data reporting. (Eds. U Riebesell, VJ Fabry, L Hansson, J-P Gattuso) 17–40. Publications Office of the European Union, Luxembourg.
.
105 IPCC (2005) IPCC special report on carbon dioxide capture and storage. .
106 Zeebe RE, Wolf-Gladrow DA (2001) CO₂ in seawater: equilibrium, kinetics, isotopes. In CO₂ in Seawater: Equilibrium, Kinetics, Isotopes. Chapter 1. Elsevier
Oceanography Series, Amsterdam, The Netherlands. .
107 GESAMP (2019) High level review of a wide range of proposed marine geoengineering techniques. (Eds. PW Boyd, CMG Vivian). IMO/FAO/UNESCO-IOC/
UNIDO/WMO/IAEA/UN/UN Environment/UNDP/ISA Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection, Rep. Stud. GESAMP
No. 98. .
108 Barker S, Ridgwell A (2012) Ocean acidification. Nature Education Knowledge 3(10), 21. .
3.1.1 Overview
There are two broad categories of OAE approaches:
electrochemical approaches and mineral addition
approaches (Figure 15).109 Electrochemical OAE approaches
work by separating seawater into basic (e.g. sodium
hydroxide, NaOH) and acidic (e.g. hydrochloric acid, HCl)
components using electrochemistry, with methods varying
based on the type of electrochemical cell used and whether
the primary medium for carbon removal is through the
basic or acidic stream.110 In contrast, mineral addition OAE
approaches involve adding alkaline rocks and materials
into the ocean, which elevates seawater pH and allows
additional atmospheric CO₂ to be taken up by the ocean.
This section focuses on one electrochemical OAE approach,
specifically electrolytic OAE, given that it has a relatively
high TRL111 and does not directly add solid material to
the ocean, which can lead to a potential perturbation of
the marine ecosystem.112 While beyond the scope of this
Roadmap, a high-level overview of promising alternative
OAE approaches and their RD&D challenges, including for
mineral addition OAE, has been provided at the end of
this section.
Figure 15: Overview of OAE approaches.
Pathway not prioritised in quantitative analysis for this approach.
Note: Chlorine is not produced due to the use of oxygen selective electrodes.
109 Eisaman MD, Geilert S, Renforth P, Bastianini L, Campbell J, Dale AW, Foteinis S, Grasse P, Hawrot O, Löscher CR, Rau GH, Rønning J (2023) Assessing the
technical aspects of ocean-alkalinity-enhancement approaches. In Guide to Best Practices in Ocean Alkalinity Enhancement Research. (Eds. A Oschlies,
A Stevenson, LT Bach, K Fennel, REM Rickaby, T Satterfield, R Webb, J-P Gattuso) Chapter 3. Copernicus Publications, State Planet. ; Karunarathne S, Andrenacci S, Carranza-Abaid A, Jayarathna C, Maelum M, Skagestad R, Haugen HA (2024) Review on CO₂ removal
from ocean with an emphasis on direct ocean capture (DOC) technologies. Separation and Purification Technology 350, 128598.
.
110 Eisaman MD et al (2023) Assessing the technical aspects of ocean-alkalinity-enhancement approaches. In Guide to Best Practices in Ocean Alkalinity
Enhancement Research. ; Karunarathne S et al (2024) Review on CO₂ removal from ocean with an emphasis
on direct ocean capture (DOC) technologies.
111 RMI (2023) The applied innovation roadmap for CDR. .
112 Lenton A, Matear RJ, Keller DP, Scott V, Vaughan NE (2018) Assessing carbon dioxide removal through global and regional ocean alkalinization under high
and low emission pathways. Earth System Dynamics 9, 339–357. .
Electrolytic OAE
In the electrolytic OAE approach, seawater is electrolysed
and separated into basic and acidic components.
The separated basic component can be discharged at
an appropriate pH and returned to the ocean, where it
captures atmospheric CO₂. The acidic component may be
sold as a byproduct but is typically neutralised with solid
materials (e.g. alkaline rocks) before being returned to
the ocean. Other byproducts of the seawater electrolysis
process can include O₂ and chlorine gas (Cl₂), as well as H₂,
which can be captured and sold as byproducts, subsidising
the cost of the OAE process.113 One OAE facility may process
a volume of seawater that is up to 147 times smaller than
the volume of air required by a direct air capture facility to
remove the same amount of CO₂ from the atmosphere.114
It does, however, require a significant amount of electricity,
primarily to power the electrolysis process.
Equatic, a US-based company specialising in OAE, has
modified this process to create a closed-loop CDR approach
(Figure 16).115 Rather than returning the basic component
to the ocean, an on-land air contactor is used to remove
CO₂ directly from the atmosphere. Atmospheric CO₂
reacts with the basic component to neutralise it while
also forming stable carbonate and bicarbonate ions.
This enables the direct measurement of the amount of
CO₂ removed, thereby improving the robustness of MRV
for this approach.116 The resulting neutralised seawater
containing carbonate and bicarbonate ions can be returned
to the ocean. A byproduct of the reaction is solid calcium
carbonate (CaCO₃), which can be separated and sold as an
additive for construction materials.117 Equatic’s closed loop
OAE process is used as the representative process for the
quantitative analysis of OAE capacity and cost in Section 11
of this Roadmap.
Figure 16: Overview of Equatic’s OAE process.118
Note: Chlorine is not produced due to the use of oxygen selective electrodes.
113 Eisaman MD et al (2023) Assessing the technical aspects of ocean-alkalinity-enhancement approaches. In Guide to Best Practices in Ocean Alkalinity
Enhancement Research. ; Karunarathne S et al (2024) Review on CO₂ removal from ocean with an emphasis
on direct ocean capture (DOC) technologies.
114 Karunarathne S et al (2024) Review on CO₂ removal from ocean with an emphasis on direct ocean capture (DOC) technologies.
115 La Plante EC, Simonetti DA, Wang J, Al-Turki A, Chen X, Jassby D, Sant GN (2021) Saline water-based mineralization pathway for gigatonne-scale CO₂
management. ACS Sustainable Chemistry & Engineering 9, 1073–1089. .
116 La Plante EC, Chen X, Bustillos S, Bouissonnie A, Traynor T, Jassby D, Corsini L, Simonetti DA, Sant GN (2023) Electrolytic seawater mineralization and the
mass balances that demonstrate carbon dioxide removal. ACS Environmental Science & Technology Engineering 3, 955–968. .
117 Equatic, EcoEngineers (2023) Equatic’s measurement, reporting, and verification methodology. White paper prepared in consultation with EcoEngineers,
August 2023. .
118 La Plante EC et al (2021) Saline water-based mineralization pathway for gigatonne-scale CO₂ management. ACS Sustainable Chemistry & Engineering 9,
1073–1089. .
3.1.2 Emerging and alternative OAE approaches
Several emerging and alternative OAE approaches at medium-high TRLs show promise for scaling and improving
energy efficiency, though further RD&D are needed. While not covered in detail in this Roadmap, approaches
such as CO₂ stripping, electrodialytic OAE, and mineral addition OAE are highlighted in Table 3 for their potential.
Table 3: Emerging and alternative OAE approaches.
APPROACH
DESCRIPTION
KEY RD&D CHALLENGES
CO₂ stripping (also
known as direct
ocean capture)
After the electrochemical separation of seawater, the acidic component
is used to acidify input seawater, catalysing the conversion of aqueous
bicarbonate in seawater into CO₂ gas, which can be captured using a vacuum
pump and durably stored in geological or mineral storage (see Section 5–7).
The decarbonised, acidified seawater is combined with the alkaline
component and returned to the ocean with a slightly higher pH level,
thereby enhancing the ocean’s capacity to absorb additional CO₂ from the
atmosphere.119 Mobile (ship-mounted) versions of this approach are also
being considered.120
Captura (US) has been leading the RD&D efforts for the CO₂ stripping
process, currently operating a third pilot project in Hawaii with the
capacity to capture 1,000 tCO₂/y, building on two previous pilot projects in
California.121 In March 2025, Captura secured an offtake agreement to deliver
30,000 carbon removal credits for Mitsui O.S.K. Lines (Japan).122
Medium TRL (TRL 6 as of
November 2023), high energy
requirement, understanding and
managing the environmental
impacts in the short- and
long‑term.123
Electrodialytic OAE
Electrodialytic OAE refers to the electrochemical separation of seawater
to produce low-concentration sodium hydroxide, hydrochloric acid and
negligible amounts of H₂ and O₂.124
Ebb Carbon (US) has been leading the RD&D efforts for the electrodialytic
OAE process. The company is scaling up a pilot project in Washington,
increasing the CDR capacity from 100 to 1,000 tCO₂/y.125 In 2024, Ebb Carbon
signed an agreement with Microsoft to remove up to 350,000 tCO₂ over the
next 10 years.126
Neutralisation of acidic
component (i.e. hydrochloric
acid) at scale.127
Mineral addition
OAE
Alkaline solid materials such as lime (CaO or Ca(OH)₂), brucite (Mg(OH)₂) and
sodium carbonate (Na₂CO₃) are dispersed into the ocean. Mineral addition
OAE increases seawater pH, allowing the ocean to take up additional
atmospheric CO₂. CO₂ reacts with seawater to form stable (bi)carbonate
ions, which can be stored for 10,000 to 100,000 years (see Section 6).128
High uncertainty on the
environmental impacts,
efficiency and MRV for
this approach.129
119 Eisaman MD et al (2023) Assessing the technical aspects of ocean-alkalinity-enhancement approaches. In Guide to Best Practices in Ocean Alkalinity
Enhancement Research.
120 Aleta P, Refaie A, Afshari M, Hassan A, Rahimi M (2023) Direct ocean capture: the emergence of electrochemical processes for oceanic carbon removal.
Energy & Environmental Science 16, 4944–4967. .
121 Captura (n.d.) Technology: Direct Ocean Capture. .
122 Captura (2025) Captura announces sale of carbon removal credits and strategic partnership with Mitsui O.S.K. Lines.
.
123 CSIRO (2022) Australia’s carbon sequestration potential: a stocktake and analysis of sequestration technologies; RMI (2023) The applied innovation roadmap
for CDR. .
124 RMI (2023) The applied innovation roadmap for CDR. .
125 Ebb Carbon (n.d.) Electrochemical ocean alkalinity enhancement for carbon dioxide removal. ; Ebb Carbon (2024)
Project Macoma secures first-of-a-kind permit for marine carbon dioxide removal. ; Ebb Carbon (n.d.) Sequim PNNL site: ocean carbon dioxide removal system deployment. .
126 Ebb Carbon (2024) Ebb Carbon signs deal with Microsoft for CO₂ removal. .
127 Eisaman MD et al (2023) Assessing the technical aspects of ocean-alkalinity-enhancement approaches. In Guide to Best Practices in Ocean Alkalinity
Enhancement Research.
128 Eisaman MD et al (2023) Assessing the technical aspects of ocean-alkalinity-enhancement approaches. In Guide to Best Practices in Ocean Alkalinity
Enhancement Research.
129 Karunarathne S et al (2024) Review on CO₂ removal from ocean with an emphasis on direct ocean capture (DOC) technologies. ; Eisaman MD et al (2023) Assessing the technical aspects of ocean-alkalinity-enhancement approaches. In Guide to Best Practices in
Ocean Alkalinity Enhancement Research. .
3.1.3 MRV capture and storage
In June 2024, Isometric published the world’s first protocol
for OAE, called Ocean Alkalinity Enhancement from Coastal
Outfalls.130 This section draws primarily on the Isometric
protocol to illustrate MRV requirements for OAE, and all
MRV‑related insights presented here are based on this
protocol unless otherwise specified. The decision to
primarily draw on MRV protocols from Isometric, rather
than those of other organisations, for OAE and other
novel CDR approaches in scope is due to Isometric being a
highly regarded global expert in MRV for CDR and having
developed a wide range of protocols. This enables a simple
but consistent structure to present how net CO₂ removal
is calculated and to illustrate the MRV nuances between
different novel CDR approaches.
In the MRV of OAE processes, the net CO₂ removal refers
to the total CO₂ removed from the atmosphere and stored,
excluding the amount of counterfactual CO₂ captured
and stored, as well as any direct CO₂ emissions from the
project. The total CO₂ removed from the atmosphere and
stored is based on the amount of increased alkalinity in
the ocean, determined through measurements taken at
the project site, as well as the quantification of additional
carbon drawdown into the ocean using ocean models.
Counterfactual CO₂ is the amount of CO₂ that would have
been removed from the atmosphere by the natural carbon
cycle of the ocean, including the interactions associated
with sediments.131
Direct CO₂ emissions from the project are associated with
the establishment and operation of the project (including
energy use), end-of-life activities such as MRV, embodied
emissions in the production and transportation of feedstock,
equipment and materials to the facility, as well as any
leakage emissions. Leakage emissions represent increased
emissions that occur when materials are diverted from other
uses, causing increased emissions elsewhere. In the case of
OAE, leakage emissions can be associated with feedstocks
(e.g. renewable electricity, rocks for neutralisation) or
consumables (e.g. electrolyser components).132
There has been progress in the development of MRV
protocols and methodologies for OAE approaches,
combining direct measurements and quantification using
ocean models. However, RD&D is still needed to account for
the challenges of operating in open environments, thereby
improving the robustness and scalability of the MRV process
for other OAE approaches.
Two leading companies in OAE approaches, Equatic and Ebb
Carbon, have also developed their own MRV methodologies.
Equatic’s MRV methodology is based on Isometric’s
Electrolytic Seawater Mineralisation protocol,133 first
released in March 2025, and is catered to closed-loop
electrolytic OAE processes (Figure 16). In their methodology,
CO₂ is measured in multiple locations, including dissolved
CO₂ in the incoming seawater to the facility, gaseous CO₂
entering the facility to react with the basic component,
and solid carbonates and aqueous bicarbonates formed
after the basic component reacts with gaseous CO₂.
Equatic uses on-stream, real-time and off-line sensors
to gather measurements of alkalinity, pH, temperature,
and salinity of the seawater and processed solutions, all
of which are entered in a model (i.e. CO₂SYS) to estimate
the CO₂ concentrations (i.e. carbonate ions, bicarbonate
ions, dissolved CO₂) in the system. Although minimal,
Equatic also considers the risk of reversal, especially the
localised secondary carbonate precipitation. Sources of
CO₂ emissions in Equatic’s operations include electricity
to power the facility, energy for grinding and transporting
rocks to the facility (for acidic component neutralisation),
and the construction of the facility.134
Ebb Carbon’s publicly available MRV methodology includes
additional comprehensive details in the calculation of the
total amount of CO₂ removal. For example, it accounts for
factors leading to OAE efficiency losses, such as alkalinity
subduction, secondary precipitation, potential acid leaks,
and/or biogeochemical feedback. It also utilises regional
ocean models and biogeochemical modules, in addition to
physical measurements of seawater parameters, to calculate
the amount of CO₂ captured and stored.135
130 Isometric (2023) Ocean alkalinity enhancement protocol v1.0: requirements and procedures for net CO₂e removal via coastal outfalls.
.
131 Isometric (2023) Ocean alkalinity enhancement protocol v1.0: requirements and procedures for net CO₂e removal via coastal outfalls.
.
132 Isometric (2023) Ocean alkalinity enhancement protocol v1.0: requirements and procedures for net CO₂e removal via coastal outfalls.
.
133 Isometric (2023) Electrolytic seawater mineralization protocol v1.0: MRV and best practices for high-quality carbon dioxide removal.
.
134 Equatic, EcoEngineers (2023) Equatic’s measurement, reporting, and verification methodology. White paper prepared in consultation with EcoEngineers,
August 2023. .; La Plante EC, Chen X, Bustillos S, Bouissonnie A, Traynor T, Jassby D, Corsini L, Simonetti DA, Sant GN (2023) Electrolytic seawater mineralization
and the mass balances that demonstrate carbon dioxide removal. ACS Environmental Science & Technology Engineering 3, 955–968. .
135 Ebb Carbon (2023) Electrochemical Ocean Alkalinity Enhancement: Measurement, reporting and verification (MRV) for Safe and Effective Carbon Dioxide
Removal. .
3.2 Enhanced rock weathering
(ERW)
The natural weathering of calcium- and magnesium-rich
silicate rocks plays an important role in the global carbon
cycle over geological timescales.136 The process begins when
CO₂ in the atmosphere is dissolved in rainwater, forming
a dilute carbonic acid. When this carbonic acid comes
into contact with calcium- and magnesium-rich silicate
rocks, the dissociation of carbonic acid forms bicarbonate
(HCO₃-) and hydrogen (H+) ions. The acid (H+) reacts with the
silicate minerals, releasing cations (e.g. Ca2+ and Mg2+) and
bicarbonate ions in the soil.137 Under alkaline conditions,
these soluble bicarbonate ions can be precipitated into
(and accumulated as) solid carbonates in soil (see Section 6,
land-based storage), or transferred through the soil system
into runoffs, feeding into rivers and oceans, where they
are durably stored (see Section 6, Ocean-based storage).138
Under acidic soil conditions, bicarbonates and carbonates
in soil can be converted back into CO₂.
3.2.1 Overview
ERW approaches involve deliberately dispersing finely
crushed rocks on land at scale,139 consequently increasing
the rate at which atmospheric CO₂ in the form of carbonic
acid is captured (Figure 17). By matching rock types with
appropriate soil characteristics, local climate and farming
practices that promote alkaline conditions, ERW aims
to accelerate natural weathering. These finely crushed
rocks have an increased surface area due to comminution
which involves crushing, grinding and milling at quarries,
and therefore have a higher weathering rate compared
to naturally occurring rocks. Depending on the size of
the crushed rocks, the weathering timescale of ERW
approaches can be decreased to years or decades as
opposed to geological timescales.140
Figure 17: Overview of the ERW process.
ERW approaches offer flexibility in terms of the applicable
feedstocks (i.e. a range of rock types and industrial
byproducts) and a range of open environments for
implementation. This section focuses on ERW approaches
for agricultural land using rocks that are purpose-mined
and ground or utilised from existing quarries, providing
an overview of the approach and its state of development.
136 Tao F, Houlton BZ (2024) Inorganic and organic synergies in enhanced weathering to promote carbon dioxide removal. Global Change Biology 30, e17132.
.
137 Holden FJ, Davies K, Bird MI, Hume R, Green H, Beerling DJ, Nelson PN (2024) In-field carbon dioxide removal via weathering of crushed basalt applied to
acidic tropical agricultural soil. Science of the Total Environment 955, 176568. .
138 Holden FJ et al (2024) In-field carbon dioxide removal via weathering of crushed basalt applied to acidic tropical agricultural soil. Science of the Total
Environment 955, 176568. ; IPCC (2005) IPCC special report on carbon dioxide capture and storage.
.
139 Holden FJ et al (2024) In-field carbon dioxide removal via weathering of crushed basalt applied to acidic tropical agricultural soil. Science of the Total
Environment 955, 176568. .
140 Buss W, Hasemer H, Ferguson S, Borevitz J (2024) Stabilisation of soil organic matter with rock dust partially counteracted by plants. Global Change Biology
30, e17052. .
This is followed by a high-level overview of alternative
ERW approaches that have the potential to enhance the
weathering efficiency, improve mining sustainability
through byproduct utilisation, and more closely align with
regional needs.
In addition to the main purpose of facilitating CDR,
agricultural ERW can deliver co-benefits for soil health and
productivity. By increasing soil alkalinity, implementing
ERW represents a complementary solution to potentially
enhance and accelerate the mitigation of soil acidification,
supporting other existing agricultural practices such as
applying crushed limestone on soil (i.e. agricultural liming)
or reducing the use of acidifying fertilisers. The weathering
of calcium- and magnesium-rich silicate rocks also supplies
nutrients to the soil, supporting plant growth and the
broader soil ecosystem.141
Agricultural ERW
Implementing ERW on agricultural land is a relevant
approach for Australia due to the prevalence of agricultural
land in proximity to suitable rock sources and the incentive
of co-benefits for soil health and agricultural production,
which could build support from farmers and landowners.
While various calcium- and magnesium-rich silicate rocks
and byproduct materials can be used in the ERW process,
basalt has high potential as a candidate for the agricultural
ERW approach in Australia. This is due to its abundance,
low concentration of potentially toxic elements, and
availability as a finely crushed byproduct of the quarrying
industry, enabling the bypassing of some capital and
operating costs associated with comminution.142 Basalt is
composed of minerals that can be weathered at a faster rate
than other felsic or sedimentary rocks, and can provide vital
nutrients for plant growth, such as magnesium, calcium,
iron, potassium and phosphorus.143 Agricultural land also
typically does not have high alkalinity (i.e. pH < 7) at the
surface level, which is an important condition for basalt to
begin weathering.144
3.2.2 Emerging and alternative ERW
processes
There are emerging and alternative ERW approaches at low
TRLs that have the potential to enhance the weathering
efficiency, improve mining sustainability through
waste utilisation, and better align with region‑specific
circumstances; however, further RD&D is needed. While not
covered in detail in this project, approaches that are
deployed at other natural environments, such as rivers and
coastlines, are highlighted in Table 4 for their potential.
Supporting RD&D in overcoming environmental and
economic uncertainties and advancing MRV methods is
important for creating a pathway to scale up emerging and
alternative ERW approaches.
Table 4: Overview of emerging and alternative ERW approaches.
APPROACH
DESCRIPTION
KEY RD&D CHALLENGES
Coastal ERW145
Dispersion of finely ground alkaline rocks onto beaches and
coastal shelves to react with dissolved CO₂ in seawater to form
bicarbonate ions.
Low TRL and uncertainties in the MRV
process and the impact on coastal and
ocean environments.
River alkalinity
enhancement146
In rivers with favourable conditions, dispersion of finely ground
alkaline feedstocks (e.g. limestone) to react with dissolved CO₂
in riverine water to form bicarbonate ions.147 River alkalinity
enhancement overlaps with the ‘Mineral addition OAE’ approach.
Low TRL and uncertainties in the MRV
process and the impact on riverine, coastal,
and ocean environments.
141 Common Capital Pty Ltd (2023) Scaling atmospheric carbon dioxide removal in New South Wales. Report prepared for the NSW Office of Energy and Climate
Change. .
142 Lewis AL, Sarkar B, Wade P, Kemp SJ, Hodson ME, Taylor LL, Yeong KL, Davies K, Nelson PN, Bird MI, Kantola IB, Masters MD, DeLucia E, Leake JR, Banwart
SA, Beerling DJ (2021) Effects of mineralogy, chemistry and physical properties of basalts on carbon capture potential and plant-nutrient element release
via enhanced weathering. Applied Geochemistry 132, 105023. ; Holden FJ, Davies K, Bird MI, Hume
R, Green H, Beerling DJ, Nelson PN (2024) In-field carbon dioxide removal via weathering of crushed basalt applied to acidic tropical agricultural soil.
Science of the Total Environment 955, 176568. .
.
143 Lewis AL et al (2021) Effects of mineralogy, chemistry and physical properties of basalts on carbon capture potential and plant-nutrient element release via
enhanced weathering. Applied Geochemistry 132, 105023.
.
144 Consultation insights.
145 RMI (2023) The applied innovation roadmap for CDR. .
146 Isometric HQ Ltd. (2025) River Alkalinity Enhancement Protocol v1.0. Isometric, London, UK. .
147 CarbonRun (n.d.) Healthy Rivers. Healthy Planet. .
3.2.3 MRV capture and storage
Isometric has developed and updated the Enhanced
Weathering in Agriculture protocol, which applies to
agricultural ERW approaches.148 This section draws primarily
on the Isometric protocol to illustrate MRV requirements for
ERW, and all MRV-related insights presented here are based
on this protocol unless otherwise specified. The decision
to primarily draw on MRV protocols from Isometric, rather
than those of other organisations, for ERW and other
novel CDR approaches in scope is due to Isometric being a
highly regarded global expert in MRV for CDR and having
developed a wide range of protocols. This enables a simple
but consistent structure to present how net CO₂ removal
is calculated and to illustrate the MRV nuances between
different novel CDR approaches.
In the MRV of agricultural ERW approaches, the net CO₂
removal is the total CO₂ removed from the atmosphere
and stored as solid or aqueous inorganic carbon in the
deployment site, excluding the amount of counterfactual
CO₂ captured and stored and any direct CO₂ emissions
from the project.
At a high level, the total CO₂ removed from the atmosphere
and stored can be quantified by measuring the amount of
cations (e.g. Ca2+ and Mg2+) released from the weathering,
or the amount of bicarbonate and carbonate ions formed.149
After the measurements are collected, they need to be
adjusted by the amount of ions temporarily or durably
lost through (bio)geochemical processes in the soil or
the amount of CO₂ released back to the atmosphere in
downstream river systems and oceans.150 Examples of such
(bio)geochemical processes in the soil include plant uptake,
clay formation, reactions of cations with acids in the soil
and carbonate mineral formation.151
Counterfactual CO₂ is the amount of CO₂ that would have
been removed from the atmosphere as a result of natural
weathering or pre-existing land practices. For example, any
CDR achieved through the common agricultural practice
of applying limestone (i.e. calcium carbonate) must be
separated from the CDR achieved through agricultural ERW
using basalt. To quantify the amount of counterfactual CO₂,
measurements from the ERW site need to be compared
against those from a control plot, which needs to be
established and maintained separately with no additional
ERW practices.152
Direct CO₂ emissions from the project are associated
with the establishment and operation of the project, as
well as end-of-life activities such as MRV and any leakage
emissions. Leakage emissions represent increased emissions
when materials (i.e. rocks) are diverted from other uses,
causing increased emissions elsewhere.153
Verification of CDR by agricultural ERW requires life
cycle and total environmental footprint analyses using
a combination of solid, liquid and gas phase analysis
methods, with key considerations including:154
• Types of feedstocks used.
• Location of ERW implementation and the surrounding
open system (including spatial and temporal changes).
• Emissions associated with the project establishment,
operation, and end-of-life activities.
• Changes in organic and inorganic carbon.
• Accurate baseline assessment, ensuring the CDR
calculations of ERW activities are additional.
• Medium-term climate changes and impacts.
• Environmental and social risks.
148 Isometric HQ Ltd. (2025) Enhanced Weathering in Agriculture Protocol v1.1. Isometric, London, UK. .
149 Common Capital Pty Ltd (2023) Scaling atmospheric carbon dioxide removal in New South Wales. Report prepared for the NSW Office of Energy and Climate
Change. .
150 Hasemer H, Borevitz J, Buss W (2024) Measuring enhanced weathering: inorganic carbon-based approaches may be required to complement cation-based
approaches. Frontiers in Climate 6, 1352825. .
151 Isometric HQ Ltd. (2025) Enhanced Weathering in Agriculture Protocol v1.1. Isometric, London, UK. .
152 Isometric HQ Ltd. (2025) Enhanced Weathering in Agriculture Protocol v1.1. Isometric, London, UK. .
153 Isometric HQ Ltd. (2025) Enhanced Weathering in Agriculture Protocol v1.1. Isometric, London, UK. .
154 Mission Innovation Carbon Dioxide Removal (CDR) Mission (2024) Measurement, Reporting and Verification (MRV) for Carbon Dioxide Removal: Issues
and Opportunities for International Harmonization of National Governments’ CDR MRV Methodologies. Mission Innovation, London, UK. ; Isometric HQ Ltd. (2025) Enhanced Weathering in Agriculture
Protocol v1.1. Isometric, London, UK. .
Additionally, the analysis and verification process
could include the co-benefits of agricultural ERW for
farm productivity to increase buy-in from farmers
and landowners.155
The MRV process for ERW approaches is challenging due to
the operation in open environments, requiring significant
RD&D to reduce costs and improve scalability. Measurement
is the most challenging step as cations, bicarbonate, and
carbonate ions often exist in low concentrations and vary
spatially, requiring extensive sample collection, which
can be time and labour-intensive, and not guaranteeing
accurate results.156 To overcome this, further RD&D can
be focused on improving soil carbon measurement
technologies and simulation models, and integrating them
into the MRV process to improve the CDR quantification.157
Despite the technical challenges with MRV, in early 2025,
the global industry’s first certified carbon credits in ERW
were delivered by startup InPlanet (Brazil, Germany),
with verification from Isometric’s Enhanced Weathering
Protocol. The transparent data and underlying information
behind each credit can be used as evidence and guidance
for future ERW operators and CDR buyers, enabling the
scaling up of ERW projects and increasing the uptake of
ERW carbon credits in the carbon market.158
155 Mission Innovation Carbon Dioxide Removal (CDR) Mission (2024) Measurement, Reporting and Verification (MRV) for Carbon Dioxide Removal: Issues and
Opportunities for International Harmonization of National Governments’ CDR MRV Methodologies. Mission Innovation, London, UK. .
156 Dietzen C, Rosing MT (2023) Quantification of CO₂ uptake by enhanced weathering of silicate minerals applied to acidic soils. International Journal of
Greenhouse Gas Control 125, 103872. .
157 Tao F, Houlton BZ (2024) Inorganic and organic synergies in enhanced weathering to promote carbon dioxide removal. Global Change Biology 30(2), e17132.
.
158 InPlanet (2025) World’s first enhanced rock weathering carbon removal credits issued. InPlanet, Brazil. ; Isometric HQ Ltd. (2025) Enhanced Weathering in Agriculture Protocol v1.1. Isometric, London, UK.
; Isometric HQ Ltd. (2025) Project profile:
Enhanced Weathering in Agriculture. Isometric, London, UK. ; Carbon Dioxide Removal Mission (2022) Carbon dioxide removal technology roadmap: innovation gaps and landscape analysis.
160 IPCC (2005) IPCC special report on carbon dioxide capture and storage. .
161 RMI (2023) The applied innovation roadmap for CDR. ; Pett-Ridge et al. (2023) Roads to
removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory. .
In the solid adsorbent DAC process, amine-based materials
are fixed to filters inside contactor modules, capturing
atmospheric CO₂ from the air as it passes through the
contactors. The contactors are then heated to 80–120°C
in a semi-vacuum environment using low-grade heat such
as steam to release high-purity CO₂ and regenerate the
amine‑based materials.161 Figure 19 illustrates the complete
DAC+S CDR approach via the solid adsorbent DAC process.
Figure 19: Overview of the DAC+S CDR approach via the solid adsorbent DAC process.
State of development
Solid adsorbent DAC using amine-based materials is one
of the leading processes for DAC globally, with many
facilities operating at pilot or early commercial scale. As of
November 2023, solid adsorbent DAC using amine-based
materials had reached a TRL range between 7 and 9.162
The most advanced solid adsorbent DAC project using
amine-based materials globally is operated by Climeworks
(Switzerland). Climeworks’s first commercial-scale DAC+S
facility in Iceland commenced operation in 2021, with an
annual capture capacity of 4,000 tCO₂/y, supported by
Carbfix (Iceland) in the storage technology.163 Their second
facility in Iceland commenced operation in 2024 with
a maximum capture capacity of 36,000 tCO₂/y.164
Other notable companies conducting pilots and
demonstrations of solid adsorbent DAC using amine-based
materials include Zero Carbon Systems (US, formerly Global
Thermostat),165 Octavia Carbon (Kenya),166 Hydrocell and
Soletair Power (Finland).167
In Australia, CSIRO has developed an innovative hybrid
solid/liquid sorbent-based process with high selectivity
for CO₂ in the atmosphere. The process is being piloted at
Santos’ Moomba operations in South Australia (SA), with a
capture capacity of 90 tCO₂/y. There are also plans to install
a second unit with an increased capacity of 365 tCO₂/y.168
162 Stakeholder consultation; RMI (2023) The applied innovation roadmap for CDR. .
163 Climeworks AG (2021) Orca: the world’s first large-scale direct air capture and storage plant. Climeworks, Zurich, Switzerland. .
164 Climeworks AG (2024) Mammoth: our newest direct air capture and storage facility. Climeworks, Zurich, Switzerland. .
165 Zero Carbon Systems (2024) Zero Carbon Systems intends to own and operate a 2,500-ton demonstration plant, a 50,000-ton commercial plant, and a
million-ton scale plant by around 2030. Zero Carbon Systems, New York, USA. .
166 Njanja A (2024) Kenya’s Octavia gets $3.9M seed to remove carbon from air. TechCrunch, 16 October. ; however, this article says the plant capacity is 1000 tpa – Payton B (2023) Kenya gears up for direct air capture push
in the Great Carbon Valley. Reuters, 13 November. ; pilot is mentioned in Applied Innovation Roadmap; Octavia Carbon (2023) Response to the Article 6.4 Supervisory Body’s
Information Note on Removal Activities. UNFCCC, Bonn, Germany. .
167 Soletair Power (n.d.) Building Carbon Capture Technology. Soletair Power, Finland. .
168 Walker S, Dawkins R (2023) Direct air captures the path to emissions targets. CSIRO, Canberra, Australia. .
Liquid absorbent DAC
Liquid absorbent DAC approaches use a liquid to capture
CO₂ from the atmosphere. This analysis primarily focuses
on the hydroxide absorbent DAC process, chosen for its
relatively advanced development stage, characterised by
medium to high TRLs.169
The hydroxide absorbent DAC process is a continuous
process where atmospheric CO₂ is reacted with a hydroxide
solution to form a solid carbonate product. The solid
carbonate product is then calcined at 700–900°C in
a calciner to release high-purity CO₂, which is subsequently
captured and transported to a geological storage or mineral
carbonation facility (see Section 5 and 7). A solid oxide
product is also formed, which can be mixed with water to
regenerate the hydroxide solution, allowing it to be reused
in multiple cycles.170 Figure 20 illustrates the complete
DAC+S CDR approach via the liquid absorbent DAC process.
Figure 20: Overview of the DAC+S approach via the liquid absorbent DAC process.
State of development
The hydroxide absorbent DAC+S approach is relatively
advanced and is being scaled up globally. As of November
2023, the hydroxide absorbent DAC process had reached
a TRL range between 7 and 9.171
The process has been developed by Carbon Engineering
(Canada), with a commercial-scale facility being constructed
in Texas since 2023 in partnership with Worley and
1PointFive. The DAC facility, STRATOS, is expected to have
the capacity to capture up to 500,000 tCO₂/y.172
In Australia, CSIRO has developed a representative approach
of the liquid absorbent DAC process, which uses amino acid
solutions (see Section 4.1.2), expected to be demonstrated
in 2026.173
4.1.2 Emerging and alternative
DAC processes
Emerging, lower-TRL DAC processes offer promising
pathways to reduce both cost and energy consumption.
Innovations such as alternative adsorbent and absorbent
materials, along with non-thermal regeneration processes
(see Table 5), are at the forefront of this progress.
While these processes require further RD&D and scale-up
efforts, they represent valuable opportunities for improving
DAC outcomes.
169 RMI (2023) The applied innovation roadmap for CDR. .
170 RMI (2023) The applied innovation roadmap for CDR. https://rmi.org/insight/the-applied-innovation-roadmap-for-cdr/; Pett-Ridge et al. (2023) Roads to
removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory. .
171 RMI (2023) The applied innovation roadmap for CDR. .
172 Carbon Engineering Ltd. (n.d.) Our Technology: Direct Air Capture. Carbon Engineering, British Columbia, Canada. ; 1PointFive (2025) STRATOS: Direct Air Capture Facility in Ector County, Texas. 1PointFive, Houston, TX. .
173 Walker S, Dawkins R (2023) Direct air captures the path to emissions targets. CSIRO, Canberra, Australia. .
Table 5: Emerging and alternative DAC processes
PROCESS
DESCRIPTION
KEY RD&D CHALLENGES
Amino acid liquid
DAC
Amino acid liquid DAC uses an amino acid solution to absorb
atmospheric CO₂, forming a carbamate compound or a
bicarbonate compound in aqueous solutions.174 The CO₂-rich
solution containing carbamate or bicarbonate compound is
then heated to 120°C using low-grade heat such as steam to
release high-purity CO₂ for storage and regenerate the amino
acid solution.175
Compared to the hydroxide absorbent DAC process, the
amino acid liquid DAC process has lower energy requirements
and a simpler process design (i.e. fewer and less complex
units of operation), resulting in potentially lower capital and
operating costs.176
Corrosivity of some amines, thermal
degradation and loss of amino
acid solution.177
Membrane DAC
Membrane DAC uses polymeric membranes to capture CO₂
from the atmosphere.178
Low capture efficiency.179
Cryogenic DAC
Cryogenic DAC uses very low temperatures to transform CO₂
from gaseous to solid state (i.e. dry ice) for capture.180
High energy requirement for cooling.181
Mineral-based solid
adsorbent DAC
Mineral-based solid adsorbent DAC uses crushed solid minerals
(e.g. calcium oxide) to react with CO₂ from the atmosphere
and form a solid carbonate product (e.g. calcium carbonate
or limestone).182
High temperature and energy intensity
requirement to process the solid carbonate
product to release the CO₂ for storage and
regenerate it to the original composition
for use in other cycles.183
Electrode-based
DAC
Electrode-based DAC uses electrochemical cells to capture and/or
release CO₂ for storage, with the potential to be integrated with
a liquid absorbent or solid adsorbent DAC process.184
Uncertainty in material cost and durability,
adsorption and regeneration kinetics, and
overall energy efficiency.185
Moisture-swing
solid adsorbent
DAC
Moisture-swing solid adsorbent DAC captures CO₂ under dry
conditions and releases CO₂ for storage under humid conditions.
Potential solid adsorbents for this process include activated
carbon, nanostructured graphite, and iron and aluminium
oxide nanoparticles.186
Potential high-water requirement if
deployed in hot and dry climates.187
The co‑production of CO₂ and water
requires separation and purification
systems and anti-corrosion materials which
can increase capital costs.188 Suitable solid
adsorbents for this process currently have
high costs.189
174 Hack J, Maeda N and Meier DM (2022) Review on CO₂ capture using amine-functionalized materials. ACS Omega.
175 Dutcher B, Fan M and Russell AG (2015) Amine-based CO₂ capture technology development from the beginning of 2013 – a review. ACS Applied Materials &
Interfaces; RMI (2023) The applied innovation roadmap for CDR. .
176 Stakeholder consultation.
177 Momeni A, McQuillan RV, Alivand MS, Zavabeti A, Stevens GW, Mumford KA (2024) Direct air capture of CO₂ using green amino acid salts. Chemical
Engineering Journal 480, Article 147934. ; Bera N, Sardar P, Hazra R, Samanta AN, Sarkar N (2024) Direct air
capture of CO₂ by amino acid-functionalized ionic liquid-based deep eutectic solvents. ACS Sustainable Chemistry & Engineering 12(38), 14288–14295.
.
178 RMI (2023) The applied innovation roadmap for CDR. .
179 CSIRO (2022) Australia’s carbon sequestration potential: a stocktake and analysis of sequestration technologies; RMI (2023) The applied innovation roadmap
for CDR. .
180 RMI (2023) The applied innovation roadmap for CDR. .
181 CSIRO (2022) Australia’s carbon sequestration potential: a stocktake and analysis of sequestration technologies; RMI (2023) The applied innovation roadmap
for CDR. .
182 RMI (2023) The applied innovation roadmap for CDR. .
183 RMI (2023) The applied innovation roadmap for CDR. .
184 RMI (2023) The applied innovation roadmap for CDR. .
185 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
186 Shindel B, Hegarty J, Estradioto JD, Barsoum ML, Yang M, Farha OK, Dravid VP (2025) Platform materials for moisture-swing carbon capture. Environmental
Science & Technology 59(9), 12345–12356. .
187 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
188 Stakeholder consultation.
189 Stakeholder consultation.
4.1.3 MRV capture and storage
Several MRV protocols have been developed to allow CDR
via DAC+S to be sold through voluntary marketplaces.
Isometric, a carbon removal registry, has developed the
Direct Air Capture protocol which applies to a broad
range of currently mature and emerging DAC processes.190
This section draws primarily on the Isometric protocol to
illustrate MRV requirements for DAC+S, and all MRV-related
insights presented here are based on this protocol unless
otherwise specified. The decision to primarily draw on
MRV protocols from Isometric, rather than that of other
organisations, for DAC+S and other novel CDR approaches
in scope is due to Isometric being a highly regarded global
expert in MRV for CDR and having developed a wide
range of protocols. This enables a simple but consistent
structure to present how net CO₂ removal is calculated
and to illustrate the MRV nuances between different novel
CDR approaches.
The Isometric protocol requires management and
documentation of emissions associated with the liquid
absorbents and solid adsorbents used. While there might
be multiple parties involved in different steps of a DAC+S
operation, the Isometric protocol requires one party to be
nominated for the entire project when applying for credits,
reducing the risk of double counting of CO₂ removal.
The system boundaries of a DAC+S project include
four components:
• DAC process, covering all activities associated with
capturing atmospheric CO₂.
• CO₂ transportation, covering all activities associated
with transporting CO₂ from the DAC facility to the
storage location.
• CO₂ storage, covering all activities associated with the
durable storage of CO₂ at the storage location (see
Section 5 and 7 for further details).
• CO₂ monitoring, covering all activities related to
monitoring CO₂ storage (see Section 5 and 7 for
further details).
The net CO₂ removal for the Isometric protocol is calculated
based on the total CO₂ stored in geological storage or the
subsurface for mineral carbonate formations, excluding the
amount of counterfactual CO₂ storage and any direct CO₂
emissions from the project.
The total amount of CO₂ captured and stored can be directly
measured using a mass flow meter or calculated using the
volume and density measurements. The density of CO₂ can
be directly measured using a calibrated density meter or
calculated using pressure and temperature measurement.
These measurement systems are readily available
off‑the‑shelf and can be integrated into the DAC facility
design to streamline the MRV process.
Counterfactual CO₂ is the amount of CO₂ removed from the
atmosphere by another DAC project and durably stored,
which is typically zero since DAC projects don’t have
competing inputs with each other or with other industries
(i.e. atmospheric CO₂).
Using the Isometric protocol, direct CO₂ emissions from
the project are associated with the system boundaries of
the project (e.g. energy use, transportation, and embodied
emissions), as well as any leakage emissions. Leakage
emissions represent increased emissions when materials
are diverted from other uses (e.g. if a DAC project uses grid
energy) or when production activity is indirectly increased
or incentivised.
The direct capture of atmospheric CO₂, the closed loop
process and the requirement for additional renewable
energy sources allow the MRV of DAC processes to be
relatively simpler than other CDR processes.
In 2023, Climeworks and Carbfix partnered with CDR
crediting platform Puro.Earth to develop an MRV
methodology for DAC+S.191 In May 2024, Climeworks
received third-party, internationally recognised certification
from Puro.Earth for its commercial facility in Iceland,
the first company in the DAC industry, establishing new
standards in the global CDR industry and enhancing
transparency and trust in the voluntary carbon market.192
190 Isometric HQ Ltd. (2025) Direct Air Capture Protocol v1.2. Isometric, London, UK. .
191 Puro.earth (2023) Climeworks selects Puro.earth to work toward certification under the Puro Standard, in collaboration with storage partner Carbfix. Puro.
earth, Helsinki, Finland. .
192 Climeworks (2024) Climeworks first DAC company to be certified under Puro Standard. .
5 Geological storage
Geological CO₂ storage involves compressing CO₂ into
a supercritical state and injecting it deep into porous
underground rock formations where it is securely
contained.193 The durability of geological CO₂ storage
systems is dictated by physical trapping mechanisms. In the
context of this Roadmap, only CO₂ that is captured from
the atmosphere for geological storage in underground
geological formations is considered. This section outlines
geological storage, reviewing it in the global and Australian
context and providing a discussion on MRV requirements.
5.1 Geological CO₂ storage
The most common geological storage formations
applicable for Australia are saline aquifers and depleted
oil and gas fields.194 Saline aquifers are deep, porous rocks
saturated with brackish to saline water where CO₂ can be
securely stored in the pore spaces between rock grains.
Depleted oil and gas fields are also porous rock reservoirs,
similar to saline aquifers, but that have previously held
hydrocarbons. They are both being used in commercial CCS
projects, because of their potential to provide reliable and
inexpensive CO₂ storage. This is largely due to their proven
ability to contain CO₂ and the potential for reuse of existing
infrastructure (e.g. wells, pipelines).
Storage of CO₂ in saline aquifers and depleted oil and gas
fields is at TRL 9,195 with the Gorgon CCS project in Western
Australia (WA) and Moomba CCS project in SA being notable
Australian examples.196 Both geological storage formations
are typically located 1–3 km below the surface, onshore
or offshore, where CO₂ remains in a dense, supercritical
state (behaving like a gas but with the density of a liquid).
The durability of geological CO₂ storage systems is dictated
by physical and chemical trapping mechanisms. As a result
of these processes, CO₂ can be durably stored in geological
formations for over 10,000 years.197 As shown in Figure 9
(matrix diagram), geological storage is typically used to store
CO₂ captured from DAC and BiCR facilities.
5.1.1 Global state of play
There is significant global potential for geological storage
to support global CDR needs. For example, the Oil and
Gas Climate Initiative’s (OGCI) 2024 CO₂ Storage Resource
Catalogue (CSRC) assessed 1,272 sites across 54 countries
for the potential capacity of geological formations to
durably store captured CO₂ using the Society of Petroleum
Engineers (SPE) Storage Resources Management System
(SRMS) classification system (see Box 4).198 Results from this
assessment indicated over 14,000 Gt of potential geological
CO₂ storage capacity worldwide. Of this, 0.052 Gt was
stored, 1.7 Gt was commercial, 625 Gt was sub-commercial,
and 13,434 Gt remained prospective/undiscovered.199
Despite the global potential for geological CO₂ storage,
the commercial readiness of geological storage resources
is low. As of 2024 and excluding CO₂-Enhanced Oil
Recovery projects, only Australia, Canada, Norway and
the US had commercial geological storage capacity.200
Challenges include lack of supporting regulatory
frameworks, limited resources for site identification and a
lack of financial incentives to undertake the activity.201
With growing global recognition of the role of geological CO₂
storage in achieving net zero targets, countries are taking
action to overcome barriers. This is reflected in the strong
growth the number of CCS projects under development,
as of the end of 2024 total number of CCS facilities in the
development pipeline was 628, an increase of over 60% on the
previous year.202 This momentum bodes well for CDR, as many
removal approaches rely on the same storage infrastructure,
regulatory frameworks, and expertise as CCS. Expansion of
CCS capacity and capability reduces costs, builds confidence,
and lays the groundwork for scaling up CDR deployment.
193 Global CCS Institute (2025) CCS explainer: storage. .
194 Fitch P, Battaglia M, Lenton A, Feron P, Gao L, Mei Y, Hortle A, Macdonald L, Pearce M, Occhipinti S, Roxburgh S, Steven A (2022) Australia’s sequestration
potential, CSIRO.
195 There are 9 ongoing projects; Fitch P et al (2022) Australia’s sequestration potential, CSIRO.
196 Gorgon see: Chevron Australia (n.d.) Gorgon Project: carbon capture and storage. ; Moomba Santos commissioned its 1.7 Mt CO₂ per year depleted gas field storage project, the world’s third-largest dedicated storage
project in Australia in 2024, and ENI NI started capture and injection of 25 000 t CO₂ per year in a depleted gas field offshore Italy with as part of the
Ravenna CCS project in Italy in 2024. See: Fitch P et al (2022) Australia’s sequestration potential, CSIRO.
197 IPCC (2005) IPCC special report on carbon dioxide capture and storage. .
198 OGCI (2024) CO₂ storage resource catalogue – Cycle 4: main report. .
199 The CSRC classifies the resource maturity of published storage resource sites using the Society of Petroleum Engineers (SPE) Storage Resources Management
System (SRMS). The CSRC SPE SRMS methodology can be found here: OGCI (2024) CO₂ storage resource catalogue – Cycle 4: main report. .
200 Characterised, discovered geological sites with active injection projects, regulatory permits, and credible commercial plans.
201 Kelemen P, Benson SM, Pilorgé H, Psarras P, Wilcox J (2019) An overview of the status and challenges of CO₂ storage in minerals and geological formations.
Frontiers in Climate 1, 9. .
202 Global CCS Institute (2024) Global status of CCS: 2024 report. .
Box 4: Determining geological resources and reserves.
Planning and implementing large-scale geological
CO₂ storage requires a clear understanding of the
total volume theoretically available in a geological
formation and the portion of that potential that can be
realistically utilised.
CO₂ storage capacity is typically classified using
resource and reserve concepts, whereby valuation
and investment require carefully considered and
standardised reporting. Correct nomenclature reports
“Resources” as the estimated quantity of a commodity
over a given time and “Reserves” as the confirmed
quantities of a commodity. Characterising the capacity
of a geological CO₂ storage site from a theoretical
resource through to a commercially viable operation,
matures as more data is gathered to reduce uncertainty
and prove the techno-economic feasibility of injection
at a specific location. Therefore, it is widely accepted
that commercial confidence in CO₂ storage capacity is
directly related to the scale of the capacity estimation
(basin-wide or site‑specific), the level of knowledge of
the sub-surface (data availability and quality), and the
stage of development of a given site (Pre-feasibility
to operational). For example, while in the early basin
screening stage, the theoretical capacity of geological
CO₂ storage is often orders of magnitude larger than the
practicable storage. When considerations such as drilling
costs, injectivity requirements (including volume and
rate), infrastructure access, resource competition, and
social acceptance are factored in, the final capacity may
end up significantly smaller.203
CO₂ storage capacity can be classified using the SPE‑SRMS
(see Figure 21). This classification system provides a
structured understanding of the relationship between
uncertainty, commercial maturity, and reported CO₂
storage capacity, and explains how storage capacity
may be contingent upon other factors. This framework
uses a horizontal range of uncertainty to reflect the
likelihood of varying storage capacities and the chance
of commerciality on the vertical axis to indicate the
likelihood of a project reaching commercialisation.
It categorises total storage resources as the estimated
quantity in geological formations, with stored values
representing CO₂ already injected into defined sites,
commercial (capacity) values indicating accessible
storage under specified conditions, sub-commercial
(contingent) values reflecting storage potential not yet
viable for commercial use, and undiscovered (prospective)
values representing potential storage capacity in
unexplored formations.
Figure 21: Resource classification framework based on the
SPE‑SRMS.204
203 Bashir A, Ali M, Patil S, Aljawad MS, Mahmoud M, Al-Shehri D, Hoteit H, Kamal MS (2023) Comprehensive review of CO₂ geological storage: exploring
principles, mechanisms, and prospects. Petroleum Science 20, 1028–1063. .
204 Bachu S, Bonijoly D, Bradshaw J, Burruss R, Holloway S, Christensen NP, Mathiassen OM (2007) CO₂ storage capacity estimation: methodology and gaps.
International Journal of Greenhouse Gas Control 1(4), 430–443. ; Other classification systems also exist,
including the Techno-Economic Resource–Reserve Pyramid. See: Clean Air Task Force (2023) Unlocking Europe’s CO₂ storage potential: analysis of optimal
CO₂ storage in Europe. .
5.1.2 Australia state of play
Australia has significant discovered and undiscovered
geological CO₂ storage resources to support CDR using
depleted hydrocarbon fields and saline aquifers. As of 2024,
analysis from the OGCI’s CSRC assessed that Australia had
9 Mt of stored CO₂, 111 Mt of commercial capacity, 31 Gt
of sub‑commercial capacity and 471 Gt of undiscovered
CO₂ storage resources.205 Australia’s stored capacity is
the second‑highest of the 54 countries assessed in the
2024 CSRC.206
For Commonwealth waters, regulations governing
geological CO₂ storage are among the most advanced
globally and were enacted under the Offshore Petroleum
and Greenhouse Gas Storage Act 2006. These regulations
are being reviewed and updated to reflect developments
in Australia’s understanding of geological CO₂ storage.
Onshore CO₂ storage regulations have been enacted in SA,
Victoria, and Queensland, are being enacted in WA and are
being considered for the Northern Territory (NT). Five GHG
storage exploration permits were awarded under the 2021
Offshore Greenhouse Gas Storage Acreage Release, and
another 10 were recently released for bidding in 2023.207
The Australian Government’s commitment to realising
Australia’s geological CO₂ storage capacity is reflected in its
May 2024 Future Gas Strategy, which includes a key action
to “promote geological storage of CO₂ and support our
region’s transition to net zero”.208
As of 2025, there were 18 geological CO₂ storage projects
in various stages of development across Australia,
highlighting the increasing technical capabilities and
support from industry and government.209 Australia’s CO₂
storage projects are associated with the production of
natural gas and liquified natural gas, H₂ and ammonia,
industrial emission sources and DAC. The majority of these
CO₂ storage projects have sufficient capacities to accept
third-party CO₂ volumes. The Gorgon Project offshore WA
was Australia’s first commercially operating project. It has
stored 11 Mt of CO₂ (as of May 2025).210 Another notable
project is the Santos’ Moomba facility in the Cooper Basin
of SA. Commencing operations in October 2024, by June
2025, it had already stored 800,000 tCO₂-e.211
5.1.3 MRV storage
MRV methodologies for geological CO₂ storage are
critical to providing assurance of durability for CDR
projects. MRV methodologies are available for all stages
of operation (pre‑injection, operation, and post-injection).
The pre-injection phase collects baseline geological and
geochemical data on the storage site to reduce uncertainty
and derisk the storage location. This information is
also used to build dynamic models that simulate CO₂
injection and storage behaviour. During the injection
phase, CO₂ injection flow rates, pressure, and plume
movement are closely monitored. After injection, the focus
shifts to monitoring CO₂ migration and preventing any
CO₂ leakage.212
Each stage of operation uses different MRV methods, but
a key purpose of monitoring the storage site during and
following injection is to verify the geological containment
of CO₂, demonstrate regulatory compliance and improve
the confidence of CDR investors and public sentiment.213
A range of tools and techniques (typically developed in the
oil and gas industry) has been demonstrated for geological
CO₂ storage.214
205 As of 2025 the Gorgon Project in WA has stored >11Mt to date and the Santos Moomba project is approaching 1 Mt, bring Australia’s total stored capacity
estimate to 12Mt. See: Chevron Australia (n.d.) Gorgon Project: carbon capture and storage. ; Santos (n.d.) Moomba carbon capture and storage. .
206 Language aligned to SRMS maturity classification (see section 2.2). Stored values represent CO₂ already injected into defined sites. OGCI (2024) CO₂ storage
resource catalogue – Cycle 4: main report. .
207 Geoscience Australia (2024) Carbon capture and storage. .
208 Department of Industry, Science and Resources (2024) Future gas strategy. .
209 Geoscience Australia (2024) Carbon capture and storage. .
210 Chevron Australia (2025) Gorgon carbon capture and storage fact sheet. .
211 Santos (2025) Moomba carbon capture and storage wins international industry recognition. .
212 IEAGHG (2024) Measurement, reporting and verification (MRV) and accounting for carbon dioxide removal (CDR) in the context of both project based
approaches and national greenhouse gas inventories (NGHGI). .
213 IEAGHG (2024) Measurement, reporting and verification (MRV) and accounting for carbon dioxide removal (CDR) in the context of both project based
approaches and national greenhouse gas inventories (NGHGI). .
214 Fitch P, Battaglia M, Lenton A, Feron P, Gao L, Mei Y, Hortle A, Macdonald L, Pearce M, Occhipinti S, Roxburgh S, Steven A (2022) Australia’s sequestration
potential, CSIRO.
6 Open environment storage
Open environment storage refers to the storage of captured
carbon in open environments, such as the ocean or on land,
in a way that prevents it from re-entering the atmosphere.215
Carbon can be stored inorganically as carbonate or
bicarbonate ions, or organically as living biomass, soil
carbon, or biochar, with different levels of durability. In the
context of this Roadmap, ERW, OAE and BiCR (i.e. slow
pyrolysis to biochar) approaches store carbon in open
environments (see Figure 9, matrix diagram), accelerating
geochemical and biological processes that are part of the
natural carbon cycle (see Figure 22).
This section outlines the storage of inorganic carbon
(on land and in the ocean) and organic carbon, along with
the MRV requirements for each. Because open environment
storage is inherently interlinked with biological and
geochemical CO₂ capture, a discussion of the global and
Australian state of development is provided in this section
for three CDR approaches, namely agricultural ERW (i.e. ERW
capture + land-based storage), electrolytic OAE (i.e. OAE
capture + ocean-based storage) and BiCR (i.e. slow pyrolysis
to biochar capture and storage).
Figure 22: Overview of the carbon cycle.216
Note: this is a simplified diagram and does not show all aspects of natural carbon cycles. It is intended to highlight the open environment carbon storage
pathways utilised by novel CDR approaches discussed in the Roadmap.
215 IEA (2025) The State of Energy Innovation. International Energy Agency, Paris. (accessed 22 October 2025)
216 Rønning JB (2024) Ocean alkalinity enhancement: tool to mitigate climate change. Ph.D. thesis. Syddansk Universitet. Det Naturvidenskabelige Fakultet.
https://doi.org/10.21996/p2f3-rp88
6.1 Inorganic and organic carbon
6.1.1 Inorganic carbon
Land-based storage
CO₂ in the atmosphere (dissolved in rainwater as carbonic
acid) can be captured and durably stored in land-based
storage (i.e. soil) as bicarbonate ions.217 Depending
on the soil pH, structure and water availability, these
soluble bicarbonate ions can be precipitated into (and
accumulated as) solid carbonates.218 Under alkaline and
stable conditions, bicarbonates and carbonates can be
naturally stored in soil for thousands to millions of years.219
However, under acidic and unstable conditions, they can
be reversed back to CO₂. An example of this is intensive
agricultural systems that increase soil acidity.220 Figure 23
illustrates the various pathways of soil carbon sequestration
as the rock weathers, based on soil pH, structure, and
water availability.
State of development
The ERW capture process (see Section 3.2.1) and land-based
CO₂ storage can be combined to form the agricultural
ERW approach for CDR. Agricultural ERW has been actively
researched and commercially pursued in Australia and
globally in recent years. As of November 2023, agricultural
ERW had reached a TRL of 7.221
Figure 23: Generalised pathways of soil carbon based on soil pH, structure and water availability.222
217 In-field carbon dioxide removal via weathering of crushed basalt applied to acidic tropical agricultural soil. Science of the Total Environment 955, 176568.
; Carbon Dioxide Removal Mission (2022) Carbon dioxide removal technology roadmap: innovation gaps
and landscape analysis; IPCC (2005) IPCC special report on carbon dioxide capture and storage. .
218 In-field carbon dioxide removal via weathering of crushed basalt applied to acidic tropical agricultural soil. Science of the Total Environment 955, 176568.
https://www.sciencedirect.com/science/article/pii/S004896972406724X?via%3Dihub - s0005; Carbon
Dioxide Removal Mission (2022) Carbon dioxide removal technology roadmap: innovation gaps and landscape analysis; IPCC (2005) IPCC special report on
carbon dioxide capture and storage. .
219 IPCC (2005) IPCC special report on carbon dioxide capture and storage. .
220 Zamanian K, Zhou J, Kuzyakov Y (2021) Soil carbonates: the unaccounted, irrecoverable carbon source. Geoderma 384, 114817. .
https://www.sciencedirect.com/science/article/pii/S004896972406724X?via%3Dihub - s0005>.
221 RMI (2023) The applied innovation roadmap for CDR. .
In Australia, the agricultural ERW approach has been
studied and trialled, with the Australian National University
having conducted a 16-week laboratory study and James
Cook University having conducted a five-year field trial
in Queensland.223 Across various incubation and field
experiments as part of the two projects, the amount of
CDR achieved ranged between 0.02 and more than 10 tCO₂
per hectare, varying based on the rock and soil types,
environmental conditions, application rates and methods,
duration, and measurement techniques.224
In 2023, the New South Wales (NSW) government funded a
study to model the State’s CDR potential via the agricultural
ERW approach. It was found that approximately 0.07 and
0.31 MtCO₂/y could be removed via the agricultural
ERW process in NSW, at a minimum cost of A$267 to
A$1,186 per tCO₂.225
An example of commercial operators in the global context
includes the US company Lithos Carbon, which utilises
ultra‑fine volcanic basalt rock dust as feedstock for
agricultural ERW. Since its founding in 2022, the company
has partnered with farmers across the US to demonstrate its
process and collect soil samples to develop MRV processes.
Lithos Carbon has signed agreements with the advanced
market commitment Frontier to remove 154,240 tCO₂
between 2024 and 2028, and separately with Microsoft to
remove 11,400 tCO₂ between 2024 and 2027.226
UNDO (UK) and Eion (US) are other startups that have
partnered with Microsoft in 2024 to support the company’s
CDR carbon-negative commitment by 2030. UNDO
dispersed 111,000 tonnes of basalt and wollastonite over
9,000 hectares of agricultural land in 2024, adding to its
cumulative estimated carbon capture total of 63,136 tCO₂.
UNDO’s partnership with Microsoft aims to remove
15,000 tCO₂ by expanding operations in the UK, Canada
and Scotland.227
Eion uses olivine imported from Norway to disperse on
agricultural land across the US. After accounting for the
emissions associated with rock extraction, comminution,
transport, spreading and natural system loss (i.e. CO₂
re‑emissions from soil), Eion’s process claims a net removal
of 84.42%, as of August 2023. Eion’s partnership with
Microsoft aims to remove 8,000 tCO₂.228 In 2025, Eion
signed an agreement with Frontier to remove 78,707 tCO₂
between 2027 and 2030.229
Ocean-based storage
The ocean is a vast and ongoing carbon reservoir, storing
approximately 38,000–40,000 Gt of inorganic carbon.230
As explained in Section 3.1, atmospheric CO₂ is captured
and stored in seawater negligibly as aqueous CO₂ and
predominantly as dissolved inorganic carbon in the forms of
bicarbonate ions (HCO₃-, ~90%) and carbonate ions (CO₃2-,
~10%). Both bicarbonate and carbonate ions can be durably
stored in the ocean over very long timescales, ranging from
10,000 to 100,000 years.231
222 In-field carbon dioxide removal via weathering of crushed basalt applied to acidic tropical agricultural soil. Science of the Total Environment 955, 176568.
223 Hasemer H, Borevitz J, Buss W (2024) Measuring enhanced weathering: inorganic carbon-based approaches may be required to complement cation-based
approaches. Frontiers in Climate 6, 1352825. ; Holden FJ, Davies K, Bird MI, Hume R, Green H, Beerling DJ,
Nelson PN (2024) In-field carbon dioxide removal via weathering of crushed basalt applied to acidic tropical agricultural soil. Biogeochemistry 167, 989–
1005. < https://www.sciencedirect.com/science/article/pii/S004896972406724X?via%3Dihub - s0005>.
224 Nelson P (2024) Spreading crushed rock over farmland can remove CO₂ from the atmosphere – if we do it right. .
225 Common Capital Pty Ltd (2023) Scaling atmospheric carbon dioxide removal in New South Wales. Report prepared for the NSW Office of Energy and Climate
Change. .
226 Lithos Carbon (n.d.) Permanent carbon capture on farms. ; Frontier Climate (2023) Lithos: enhancing weathering for
permanent carbon removal. ; Lithos Carbon (2024) Lithos Carbon researching carbon removal using enhanced
rock weathering for Microsoft. .
227 The public announcement of the partnership did not disclose the period over which ERW needs to be done and CDR achieved. See: UNDO Carbon (n.d.)
Enhanced rock weathering. ; UNDO Carbon (2024) 2024 in review: progress, partnerships, and pioneering
carbon removal solutions. ; UNDO
Carbon (2024) UNDO signs follow-on enhanced rock weathering carbon removal deal with Microsoft. .
228 The public announcement of the partnership did not disclose the period over which ERW needs to be done and CDR achieved. See: Eion Carbon (2024)
Calculating Eion’s carbon impact: our life cycle assessment. ; Eion Carbon (2024) Eion signs deal to
deliver carbon removal credits to Microsoft. .
229 Frontier Climate (2025) Frontier buyers sign $33M in offtake agreements with Eion. .
230 Shadwick E, Rohr T, Richardson A (2023) Oceans absorb 30% of our emissions, driven by a huge carbon pump. CSIRO. .
The amount stored in each form of CO₂ is a function of the
seawater pH (Figure 14). The increase in CO₂ in the ocean
since the preindustrial period has resulted in a decline in
ocean pH (ocean acidification), along with a decrease in
the concentration of carbonate ions.232 However, on much
longer timescales, the natural weathering of silicate rocks
is believed to have led to an increase in pH through the
addition of soluble bicarbonate ions via run-off, which
in turn reduced atmospheric CO₂ levels and increased
the amount of CO₂ stored in the ocean. This is termed
ocean alkalinisation.
State of development
The electrolytic capture process (see Section 3.1.1) and
ocean-based CO₂ storage can be combined to form the
electrolytic OAE approach for CDR. Electrolytic OAE
is rapidly advancing globally, with growing efforts
predominantly from US companies to demonstrate and
scale up processes. As of November 2023, electrolytic OAE
had reached a TRL of 6.233
Globally, Equatic (US) has been leading the RD&D
and scaling up of electrolytic OAE.234 In early 2024,
it began constructing the world’s largest ocean-based
demonstration facility in Singapore with a removal
capacity of 3,650 tCO₂/y, leveraging the learnings and
some built infrastructure from two previous pilot projects
in Singapore and Los Angeles. In mid-2024, Equatic
partnered with CDR project developer Deep Sky (Canada)
to commence engineering for North America’s first
commercial-scale OAE facility in Quebec.235 The facility is
expected to remove 109,500 tCO₂ from the atmosphere
and produce 3,600 tonnes of green H₂ per year once
operational, targeting a pathway to achieve CDR at less
than US$100 per tonne by 2030.236
In Australia, CSIRO’s CarbonLock is developing a flexible,
mobile, modular testbed system to explore a range of OAE
approaches. The research project combines modelling and
observations to evaluate sites, optimise the process, assess
impacts on surrounding environments, and support the
development of an MRV framework.237
6.1.2 Organic carbon
Forest and soil carbon (conventional CDR)
Australia’s forests contain a substantial amount of carbon
in above-ground and below-ground carbon pools. As of
2021, a total stock of 19,147 Mt was estimated to be stored
in native forests (98.9%), plantations (1.0%) and other
forests (0.1%).238 One of the most important carbon
pools in forests is living plant tissue. Plants store most
of their carbon in woody plant tissues like tree trunks,
roots and large branches. A portion of the carbon in
living tissues will accumulate as leaf litter and coarse
woody debris, eventually decaying and either feeding the
forest soil‑carbon pool or returning to the atmosphere
(see Figure 22).
While increasing the long-term storage of carbon in
forests and soils can contribute to reducing atmospheric
concentrations of CO₂, this type of storage has low
durability (10–100 years) and a high risk of reversal.
Forest and soil carbon pools are increasingly vulnerable to
climate change, extreme weather events and human-related
activities that cause disturbances and release CO₂ back into
the atmosphere.239
231 IPCC (2005) IPCC special report on carbon dioxide capture and storage. .
232 Hurd, Catriona; Lenton, AA; Tilbrook, B; Boyd, Philip (2018) Current understanding and challenges for oceans in a higher-CO₂ world. University of Tasmania.
Journal contribution. .
233 RMI (2023) The applied innovation roadmap for CDR. .
234 Equatic (n.d.) The Equatic process. .
235 Equatic (2024) Equatic unveils plans for the world’s largest ocean-based carbon removal plant. .
236 Equatic (2024) Equatic to build North America’s first commercial-scale ocean-based carbon removal facility. ;; Deep Sky (2024) Equatic to build North America’s first commercial-scale ocean-based carbon
removal facility. .
237 CSIRO (2023) Enhancing alkalinity for ocean-based carbon dioxide removal. .
238 Montreal Process Implementation Group for Australia (MIG) and National Forest Inventory Steering Committee (NFISC) (2024) Indicator 5.1a: Contribution of
forest ecosystems and forest industries to the global greenhouse gas balance. Australia’s State of the Forests Report. Australian Bureau of Agricultural and
Resource Economics and Sciences, Canberra. .
239 Montreal Process Implementation Group for Australia (MIG) and National Forest Inventory Steering Committee (NFISC) (2024) Indicator 5.1a: Contribution of
forest ecosystems and forest industries to the global greenhouse gas balance. Australia’s State of the Forests Report. Australian Bureau of Agricultural and
Resource Economics and Sciences, Canberra. .
Biochar
A more durable example of land-based open storage
is when CO₂ stabilised in biochar is applied to soil and
stored as a long-lived carbon product.240 The application
of biochar to soil offers numerous co-benefits for soil
health and agricultural productivity, including improving
soil physicochemical properties (e.g. porosity, bulk
density, pH, cation exchange capacity), nutrient availability
and microbial activity, as well as supporting pollutant
adsorption and soil remediation, and reducing soil N₂O
emissions and fertiliser requirements.241
There is evolving research on the durability of biochar
as a CO₂ storage medium. The general consensus is
that biochar can durably store carbon for 100 years or
above, with Microsoft currently categorising biochar as a
medium‑durability storage solution (i.e. 100–1,000 years).242
However, Sanei et al. (2024) found that the durability of
biochar can be extended to 100 million years in highly
oxidising environments and even more in non-highly
oxidising environments, noting that 50% of carbon is
assumed to be degraded or lost throughout this period.243
While the partially contained soil environment in which
biochar is applied can impose some risk of reversal into
CO₂, in reality the carbon contained in biochar is likely to
end up more securely stored in sediments.244 As a result,
the risk of reversal for carbon in biochar is potentially lower
than for conventional CDR approaches.
240 Pett-Ridge et al. (2023) Roads to removal: options for carbon dioxide removal in the United States. Lawrence Livermore National Laboratory.
.
241 Li X, Wu D, Liu X, Huang Y, Cai A, Xu H, Ran J, Xiao J, Zhang W (2024) A global dataset of biochar application effects on crop yield, soil properties, and
greenhouse gas emissions. Scientific Data 11(1), 1–8. ; Omokaro GO, Kornev KP, Nafula ZS, Chikukula AA,
Osayogie OG, Efeni OS (2025) Biochar for sustainable soil management: Enhancing soil fertility, plant growth and climate resilience. Farming System 3(4),
100167. .
242 Microsoft (n.d.) Carbon removal program. .
243 Sanei H, Rudra A, Przyswitt ZMM, Kousted S, Sindlev MB, Zheng X, Nielsen SB, Petersen HI (2024) Assessing biochar’s permanence: An inertinite benchmark.
International Journal of Coal Geology 281, Article 104409. .
244 Stakeholder consultation.
State of development
Slow pyrolysis to biochar is one of many BiCR+S approaches.
It combines the capture of CO₂ during biomass growth
with conversion to biochar during the slow pyrolysis
process. This biochar can be applied to soil and stored as
a long‑lived product. Slow pyrolysis to biochar is currently
one of the leading CDR approaches nationally and globally,
with a thriving market and growing opportunities for
carbon credits.
In 2023, the Australia New Zealand Biochar Industry Group
(ANZBIG) delivered the Australian Biochar Industry Roadmap
2030, bringing together perspectives of (predominantly)
companies and industry groups. The Australian Biochar
Industry Roadmap 2030 outlines the key initiatives and
actions to scale the existing Australian biochar industry,
which was estimated to produce 10,000 to 20,000 tonnes
of biochar per year in 2020 and valued at A$50 million
in 2023, into a multibillion-dollar industry in 2030
(i.e. estimated to be at least A$1–5 billion per year).245
In Kangaroo Island (SA), Re-Vi is leading one of the
world’s largest biochar for CDR projects, converting
4.5 Mt of bushfire-damaged timber into high-quality,
agricultural‑grade biochar and removing 2 Mt of CO₂ from
the atmosphere.246
In WA, Biomass Projects, with support from Residual, is
developing a commercial-scale biochar production project
with the expectation of removing 500,000 tCO₂/y by
2028, using the invasive species of mesquite as the key
biomass feedstock. The project has also received support
from Carbonfuture, particularly in integrating digital
MRV services.247
Rainbow Bee Eater, a Melbourne-based company, has
developed a modular pyrolysis system to produce biochar
for CDR. In 2020, the company became the first biochar
carbon removals supplier outside Europe certified by
Puro.earth, with purchasers including Shopify, Microsoft
and others.248
The International Biochar Initiative and the US Biochar
Initiative reported that at least 350,000 tonnes of biochar
were produced in 2023, with a compound annual growth
rate of 91% from 2021 to 2023. This growth rate is equivalent
to 600,000 tCO₂ removed from the atmosphere in 2023;
however, only a small portion of this was likely registered
as carbon credits, despite the growing biochar carbon
credit market. Key identified focus areas to unlock industry
growth include market development, high-quality biochar,
and access to capital.249
6.1.3 MRV storage
The MRV for CDR approaches that disperse captured
carbon in open environments is complex. The mechanics
of the natural carbon cycle make it hard to distinguish
added carbon from natural fluctuations and determine
additionality. CO₂ is often dispersed over large areas,
making MRV expensive and logistically complex. In terms
of ocean-based storage, observations alone are considered
insufficient to quantify net removals. Numerical simulations
are also required; however, these face large uncertainties
and data gaps. Similarly, the MRV of land‑based storage
faces difficulties in predicting and measuring variables
such as background flux, rates of weathering, and
alkalinity production. MRV of CDR approaches that
use open environment storage still require significant
RD&D. For more information on the current state of MRV
development for these approaches, see Section 2.1.2–4.1.3.
For specific actions and recommendations to improve MRV,
refer to Section 14.
245 ANZBIG (2023) Australian Biochar Industry 2030 Roadmap. ANZ Biochar Industry Group.
.
246 Re-Vi Group (2025) Kangaroo Island Project. .
247 Biomass Projects (2025) Transforming invasive species into carbon-capturing biochar. ; Carbonfuture (2025) Turning
invasive plants into climate action: Carbonfuture MRV+ to track Australia’s landmark biochar carbon removal project at half a million tonnes annually.
.
248 Rainbow Bee Eater (n.d.) What we do. ; Rainbow Bee Eater (2025) Achievements.
.
249 International Biochar Initiative (IBI) & US Biochar Initiative (USBI) (2024) 2023 Global Biochar Market Report. BioCycle. ; Global Biochar Market Report. .
7 Mineral storage
Mineral storage refers to approaches that lock away
atmospheric CO₂ through mineral carbonation (or carbon
mineralisation). Mineral carbonation reactions occur in
nature, as a product of rock weathering at the earth’s
surface (see Section 3.2) or in groundwater systems that
come into direct contact with dilute carbonic acid in
rainwater or CO₂-rich groundwater. In addition to rock
weathering at the (near) surface, mineral carbonation
reactions also occur during rock-forming processes,
where CO₂-rich hydrothermal fluids from deep in the
earth’s crust react with subsurface rocks at elevated
pressures and temperatures.
The fundamental principles of naturally occurring mineral
carbonation reactions can be engineered to store CO₂ as
carbonate minerals in shorter time frames than observed
in natural analogues. Mineral storage solutions include
CO₂-reactive underground rock formations, mine tailings,
and durable carbonate materials or products. This section
outlines in-situ (below-ground) mineral carbonation and
two ex-situ (above-ground) approaches: accelerated and
passive mineral carbonation. The global and Australian
context for each approach will also be reviewed, along with
MRV requirements.
While these mineral carbonation approaches are not
included in this Roadmap’s cost and capacity analysis due
to a lack of data availability, their emerging importance is
strongly acknowledged. Accordingly, potential next steps,
actions, and considerations to scale this CDR approach have
been provided in Section 13.5.
7.1 Mineral carbonation
7.1.1 In-situ mineral carbonation
In-situ mineral carbonation involves injecting aqueous
CO₂ into shallow, permeable mafic and ultramafic rock
formations underground. Mafic and ultramafic rock
types include basalt/dolerite and peridotite/komatiite
or serpentinite (hydrated peridotite), respectively, which
are abundant throughout Australia250 and globally,251
and exist in alternative locations that lack conventional
geological storage.252
Mafic and ultramafic rock formations offer durable and
secure CO₂ storage.253 This is due to the high concentrations
of divalent cations such as Mg2+ and Ca2+ present in the
rock-forming minerals, which are reactive to aqueous
CO₂.254 Unlike geological CO₂ storage, where supercritical
CO₂ is primarily structurally and stratigraphically trapped
within the pore spaces between the grains of sedimentary
rocks,255 in-situ mineral carbonation traps aqueous CO₂
primarily through carbonate mineralisation.256 Injection of
aqueous CO₂ achieves solubility trapping immediately, and
in Icelandic basalts, mineralisation of >95% CO₂ has been
demonstrated within 2 years.257
Australian basalts are, in general, older, colder, less porous,
and less permeable than Icelandic basalts due to their
age, geological setting, and often complex and protracted
histories of metamorphism, deformation, and alteration.
However, delineation of suitable mafic and ultramafic
geology in Australia is ongoing.258 Australian serpentinite
formations are a potentially favourable alternative,259
forming significant proportions of Australia’s east coast.260
250 Thorne JP, Highet LM, Cooper M, Claoué-Long JC, Hoatson DM, Jaireth S, Huston DL, Gallagher R (2014) The Australian Mafic-Ultramafic Magmatic Events GIS
Dataset: Archean, Proterozoic and Phanerozoic Magmatic Events. Geoscience Australia. .
251 Oelkers EH, Gislason SR, Matter J (2008) Mineral carbonation of CO₂. Elements 4(5), 333–337. .
252 Budinis S, Krevor S, Mac Dowell N, Brandon N, Hawkes A (2018) An assessment of CCS costs, barriers and potential. Energy Strategy Reviews 22, 61–81.
.
253 Matter JM, Kelemen PB (2009) Permanent storage of carbon dioxide in geological reservoirs by mineral carbonation. Nature Geoscience 2(12), 837–841.
; Snæbjörnsdóttir SÓ, Sigfússon B, Marieni C, Goldberg D, Gislason SR, Oelkers EH (2020) Carbon dioxide storage through
mineral carbonation. Nature Reviews Earth & Environment 1(2), 90–102. ..
254 Klein F, McCollom TM (2023) From serpentinization to carbonation: New insights from a CO₂ injection experiment. Science of The Total Environment 901,
165262. .
255 NASEM, 2019
256 Kelemen P, Benson SM, Pilorgé H, Psarras P and Wilcox J (2019) An Overview of the Status and Challenges of CO₂ Storage in Minerals and Geological
Formations. Front. Clim. 1:9.
257 Sigfusson B, Gislason SR, Matter JM, Stute M, Gunnlaugsson E, Gunnarsson I, Aradottir ES, Sigurdardottir H, Mesfin K, Alfredsson HA, Wolff-Boenisch
D, Arnarsson MT, Oelkers EH (2015) Solving the carbon-dioxide buoyancy challenge: The design and field testing of a dissolved CO₂ injection system.
International Journal of Greenhouse Gas Control 37, 213–219. .
258 CSIRO (2023) Identifying the geological properties of ultramafic rocks for carbon storage potential. CarbonLock Future Science Platform. ; CSIRO (2024) Putting Australian enhanced mineralisation on the map. .
259 Lacinska AM, Styles MT, Bateman K, Hall M, Brown PD (2017) An experimental study of the carbonation of serpentinite and partially serpentinised
peridotites. Frontiers in Earth Science 5, Article 37. .
260 Austin et al., 2025 (in prep)
7.1.2 Global state of development
In-situ mineral carbonation offers significant potential
for CO₂ storage, but it is less developed than geological
CO₂ storage and is commercially operating at a kilotonne
scale globally. The global potential of CO₂ storage via
in-situ mineral carbonation (using certain rock types) are
estimated to be between 1.1 and 4.5 GtCO₂/y.261 According
to the International Energy Agency’s (IEA) State of Energy
Innovation report, storage capacity in basalts and peridotites
alone could grow from around 0.02 MtCO₂/y in 2024
to 2.5 MtCO₂/y by 2030.262 Nonetheless, it is difficult to
determine the TRL of mineral carbonation, as this sector is
relatively emerging, with only a handful of companies and
dedicated funding resources exploring this storage pathway.
Since 2012, the Wallula project (US) and Carbfix (Iceland)
have been injecting CO₂ into basalt.263 Carbfix, an
academic‑industrial partnership, pioneered a novel
approach of in-situ mineral carbonation by dissolving CO₂
in water and injecting it into subsurface basalt formations.
Since then, Carbfix pilot tests have shown that up to 95%
of injected CO₂ is fully carbonated in under two years.264
The Wallula project injected supercritical CO₂ into the
basalt formation, with modelling indicating over 60% of the
CO₂ would mineralise within 2 years.265 Results from a recent
pilot test in the Samail ophiolite, Oman, demonstrate rapid
mineralisation of CO₂ (>88% mineralised within 45 days) in
partially to pervasively serpentinised peridotites.266
Iceland is considered the global leader in in-situ mineral
carbonation, with Carbfix storing 4,000 tCO₂/y from
Climeworks’ Orca DAC facility, and up to 36,000 tCO₂/y
from Climeworks’ Mammoth DAC facility, since
commissioning in May 2024.267 The Coda Terminal, Carbfix’s
cross-border carbon transport and storage hub in Iceland,
currently in advanced development, is anticipated to store
300,000 tCO₂/y by 2032.268
Fitch P, Battaglia M, Lenton A, Feron P, Gao L, Mei Y, Hortle A, Macdonald L, Pearce M, Occhipinti S, Roxburgh S, Steven A (2022) Australia’s sequestration
potential, CSIRO.
261 IEAGHG (2024) Measurement, reporting and verification (MRV) and accounting for carbon dioxide removal (CDR) in the context of both project-based
approaches and national greenhouse gas inventories (NGHGI). Technical Report 2024-09, October 2024. IEA Greenhouse Gas R&D Programme, Cheltenham,
UK. .
262 IEA (2024) The State of Energy Innovation. International Energy Agency, Paris, France. .
263 IEAGHG (2017) Review of CO₂ Storage in Basalts. Technical Report 2017-TR2. IEA Greenhouse Gas R&D Programme, Cheltenham, UK.
.
264 Carbfix (n.d.) Our story. ; Carbon Capture Journal (2019) CarbFix project turns CO₂ into rock.
.
265 White SK, Spane FA, Schaef HT, Miller QRS, White MD, Horner JA, McGrail PB (2020) Quantification of CO₂ mineralization at the Wallula Basalt Pilot Project.
Environmental Science & Technology 54, Issue 22, 14609–14616. .
266 Matter JM, Speer J, Day C, Kelemen PB, Ibrahim A, Al Mani S, Tasfai E, Ilyas M, Khimji K, Hasan T (2025) Rapid mineralisation of carbon dioxide in peridotites.
Communications Earth & Environment 6, Article 590. .
267 Carbfix (2024) World’s largest direct air capture plant switches on in Iceland. .
268 Global CCS Institute (2024) Global Status of CCS 2024. Global CCS Institute, Melbourne, Australia. ; Fitch P, Battaglia M, Lenton A, Feron P, Gao L, Mei Y, Hortle A, Macdonald L, Pearce M, Occhipinti S, Roxburgh S, Steven A (2022)
Australia’s sequestration potential, CSIRO; Carbfix (n.d.) Coda Terminal: A scalable onshore CO₂ mineral storage hub in Iceland. .
7.1.3 Australian state of development
Research on in-situ CO₂ mineralisation in Australia
is limited, with the majority of existing mineral
carbonation research focusing on ex-situ applications.269
However, CSIRO’s CarbonLock Future Science Platform is
investigating in-situ CO₂ mineralisation in basaltic and
serpentinite formations to provide evidence for future
investment. It is developing a publicly available resource
map to support site selection.270 Furthermore, Australia is
co-leading the Carbon Mineralisation Technical Track within
Mission Innovation’s CDR Mission.271
7.1.4 MRV – storage
Similarly to geological CO₂ storage, a range of
techniques capable of detecting CO₂ is used for
in‑situ mineral carbonation MRV (see Section 5.1.3).
However, as mineralisation of CO₂ is the dominant trapping
mechanism, reactive and non-reactive geochemical and
isotopic tracers (and geochemical analyses) are required to
monitor CO₂ mineralisation, as opposed to conventional
MRV methods used to monitor CO₂ containment
(e.g. seismic imaging).272 Long-term monitoring of mineral
storage sites is significantly reduced once mineralisation of
CO₂ is verified, as the risk of CO₂ leakage is eliminated.273,274
7.2 Ex-situ mineral carbonation
Ex-situ mineral carbonation involves reacting CO₂ with
suitable mineral or alkaline feedstocks to produce stable
carbonates in above-ground, controlled environments
that accelerate mineral carbonation reaction rates and
efficiency. Ex-situ mineral carbonation can be applied to
a wide range of magnesium- and calcium-rich silicate rocks
as well as mining and industrial wastes, including mine
tailings, iron/steel slag, pulverised fuel ash, cementitious
materials, and incinerator waste.275 Ex-situ mineral
carbonation generally requires a source of concentrated
CO₂, although this is not always the case.
Accelerated mineral carbonation (AMC) or engineered
ex-situ mineral carbonation is conducted in a controlled
aqueous environment (i.e., in water) to enhance
reaction rates, with the optional addition of heat and
pressure to further increase reactivity.276 AMC can be
applied to pure CO₂ gas streams or CO₂-containing
flue gas from industrial processes; however, CO₂ must
be sourced from the atmosphere to be considered
CDR. Additive salts, such as sodium chloride, sodium
bicarbonate, ammonium (bi)sulphate, or organic acids,
can be optionally used to adjust the pH, improve the
extent of carbonation, and reduce reaction time.
AMC can be carried out in one or multiple reactors.
The use of multiple reactors can help enhance the reaction
rate by altering the solution chemistry or mineral structure,
thereby making the reactants more reactive. However, the
multi-reactor approach can be energy intensive.277
269 Al Kalbani M, Serati M, Hofmann H, Bore T (2023) A comprehensive review of enhanced in-situ CO₂ mineralisation in Australia and New Zealand.
International Journal of Coal Geology 265, Article 104316. .
270 CSIRO (2024) Putting Australian enhanced mineralisation on the map. .
271 CSIRO (2023) Mission Innovation – Carbon Dioxide Removal (MI-CDR) engagement. CarbonLock Future Science Platform. .
272 Matter JM, Stute M, Snæbjörnsdottir S, Oelkers EH, Sigurdur R, Gislason SR, Aradottir ES, Sigfusson B, Gunnarsson I, Sigurdardottir H, Gunnlaugsson
E, Axelsson G, Alfredsson HA, Wolff-Boenisch D, Mesfin K, Fernandez de la Reguera Taya D, Hall J, Dideriksen K, and Broecker WS (2016) Rapid carbon
mineralization for permanent disposal of anthropogenic carbon dioxide emissions. Science352, 1312-1314 (2016). .
273 Burton M and Bryant SL (2009) Surface dissolution: Minimizing groundwater impact and leakage risk simultaneously, Energy Procedia, Volume 1, Issue 1,
2009. 3707-3714, ISSN 1876-6102. .
274 Gunnarsson I, Aradóttir ES, Oelkers EH, Clark DE, Arnarson MP, Sigfússon B, Snæbjörnsdóttir SO, Matter JM, Stute M, Júlíusson BM, and Gíslason SR (2018)
The rapid and cost-effective capture and subsurface mineral storage of carbon and sulfur at the CarbFix2 site. International Journal of Greenhouse Gas
Control, Volume 79, 2018. Pages 117-126. ISSN 1750-5836. .
275 Milani D, McDonald R, Fawell P, Weldekidan H, Puxty G, Feron P (2025) Ex-situ mineral carbonation process challenges and technology enablers: A review
from Australia’s perspective. Minerals Engineering 222, Article 109124. .
276 Yadav S, Mehra A (2021) A review on ex situ mineral carbonation. Environmental Science and Pollution Research 28(10), 12202–12231.
277 Milani D, McDonald R, Fawell P, Weldekidan H, Puxty G, Feron P (2025) Ex-situ mineral carbonation process challenges and technology enablers: A review
from Australia’s perspective. Minerals Engineering 222, Article 109124. .
Passive ex-situ mineral carbonation simulates the rock
weathering reaction that occurs in natural environments
using alkaline mining or industrial waste. Passive ex-situ
mineral carbonation or enhanced weathering typically does
not require a concentrated stream of CO₂, as the alkaline
material will passively react with CO₂ in the atmosphere.
However, due to the slow reaction rate and low efficiency
of natural processes, additional steps or methods are
often required, such as manipulating the reactive material
(e.g. tailings) to increase the exposed material surface
area or applying heat to activate the material and thereby
enhance reactions. The materials can then be left in
mine-site pits to weather before being buried to store CO₂
durably, or they can be spread in a humidified enclosed
facility for weathering and later transferred to storage
locations.278 While ERW can be regarded as type of ex-situ
(above‑ground) mineral carbonation,279 for the purpose of
this Roadmap, it has been categorised independently (see
Section 3.2).
7.2.1 Global state of development
A number of ex-situ mineral carbonation demonstration
and pilot projects are currently operating globally, with
many innovations in system and process design supporting
the scale up to commercial deployment before the end of
the decade. An example in the global context is Paebbl,
a Dutch start-up focused on developing on-site ex-situ
mineral carbonation units that can be integrated into a
high-emission source or a DAC facility. Paebbl’s technology
produces a carbonate material that can replace cement and
other cementitious materials in the concrete mix, storing
300 kg of CO₂ per tonne of carbonate material produced.280
Paebbl has been operating a pilot and demonstration
facility in Rotterdam, which was scaled up to be continuous
and capable of capturing 500 tCO₂/y in March 2025.
There are plans for a commercial facility to be completed
in 2028.281
7.2.2 Australian state of development
MCi Carbon is an Australian CCU company that uses a
low-temperature, low-pressure AMC process to produce
high-value carbonate and/or silica products.282 MCi Carbon
currently plays a fundamental role in decarbonising
hard‑to-abate industrial emitters. However, it is expected
that the process may be adapted to operate with DAC
systems, therefore meet the definition of CDR in the near
future. In 2023, MCi Carbon commenced construction of
one of the world’s first mineral carbonation demonstration
facilities in Newcastle, which has the expected capacity
of storing over 1,000 tCO₂/y in carbonate products.283
In 2024, MCi Carbon was awarded A$14.5 million
through the Australian Government’s Carbon Capture
Technologies Program to expand and optimise
processing capabilities at its Newcastle facilities.284
MCi Carbon has also signed a long‑term strategic
cooperation agreement with refractory company RHI
Magnesita (Austria) to deploy its technology at commercial
scale in Austria, including plans for a commercial-scale
facility capable of storing 50,000 tCO₂/y in carbonate
products from 2028.285
278 Common Capital Pty Ltd (2023) Scaling atmospheric carbon dioxide removal in New South Wales. Report prepared for the NSW Office of Energy and Climate
Change. .
279 World Economic Forum (2023) 5 things to know about carbon mineralization.