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Technology

What is it?

An electric current is supplied to isolated nitrogenase enzymes, which reduce nitrogen gas (N2) and water to form ammonia, whilst also producing hydrogen.

Why is it important?

Ammonia can be synthesised under ambient conditions via the application of an electric current.

Characteristics

  • Volumetric hydrogen density: High (10.7kg H2 / m3 at 10 bar and 25°C)
  • Gravimetric hydrogen density: High (17.8% by mass)
  • Storage conditions: Liquid at ambient temperature, 10-11 bar pressure

Benefits

  • Occurs at ambient temperature and pressure. Less energy intensive than Haber-Bosch
  • Occurs at neutral pH

Limitations

  • Separation of ammonia and hydrogen required after production
  • Biological system is difficult to control
  • Metallo-protein is oxygen sensitive and usually negated by biology

RD&D priorities

  • Separation of ammonia and hydrogen required after production
  • Biological system is difficult to control
  • Metallo-protein is oxygen sensitive and usually negated by biology

Known active organisations

  • CSIRO

Other opportunities like this

  • Ammonia is synthesised by reacting hydrogen with nitrogen gas at high temperatures and pressures.

  • Hydrogen is reacted with toluene to form methylcyclohexane (MCH), a compound that can be transported at ambient temperature and pressure.

  • Methanol is conventionally synthesised at large scale from synthesis gas (or syngas), a mixture of hydrogen and carbon monoxide typically at an H₂/CO ratio of 1.8 ~ 2.2, derived through steam reforming of natural gas or steam gasification of coal.

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