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Technology

What is it?

An electric current is supplied to isolated nitrogenase enzymes, which reduce nitrogen gas and water to form ammonia, whilst also producing hydrogen.

Why is it important?

Haber-Bosch synthesis is a well-established industrial process that has been optimised for hydrogen production.

Characteristics

  • Volumetric hydrogen density: High (10.7kg H2 / m3 at 10 bar and 25°C)
  • Gravimetric hydrogen density: High (17.8% by mass)
  • Storage conditions: Liquid at ambient temperature, 10-11 bar pressure
  • Synthesis energy efficiency: Production of hydrogen via SMR paired with Haber-Bosch synthesis has an overall energy efficiency of approximately 61-66%

Benefits

  • Established industrial process

Limitations

  • High operating temperature and pressures, highly energy-intensive
  • Generates large amounts of carbon dioxide
  • Diminishing returns expected from improvements to this synthesis method

RD&D priorities

  • Improve catalyst development
  • Integrate with renewable sources of hydrogen

Known active organisations

  • The Australian National University
  • The University of New South Wales
  • The University of Western Australia

Other opportunities like this

  • Hydrogen is reacted with toluene to form methylcyclohexane (MCH), a compound that can be transported at ambient temperature and pressure.

  • Methanol is conventionally synthesised at large scale from synthesis gas (or syngas), a mixture of hydrogen and carbon monoxide typically at an H₂/CO ratio of 1.8 ~ 2.2, derived through steam reforming of natural gas or steam gasification of coal.

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